Role of brine composition on rock surface energy and its implications for subcritical crack growth in calcite

Subcritical crack growth in calcite-bearing reservoirs plays a vital role in rock deformation. Published experimental results show that fluid-rock interaction likely affects rock surface energy and triggers fracture propagation. However, much of research up to now has been only descriptive in nature, impairing a substantial interpretation to predict subcritical crack growth. In this study, we developed a physicochemical model to relate fluid-calcite interaction in particular surface potential to surface energy in light of capacitance theory. To test the model, we calculated calcite surface chemical species and surface potential as a function of pH, ion type and fluid salinity using surface complexation modeling. Moreover, we compared the predicted surface energy with Bergsaker et al.'s experimental measurements. Our results confirm that fluid chemistry would affect calcite surface species distribution and surface energy. At high acidic condition, lowering salinity increases surface potential of brine-calcite. At alkaline condition, lowering salinity decreases surface potential in the presence of MgSO4 and MgCl2 but increases that of Na2SO4. Furthermore, pH would affect the level of bonding-capable divalent such as Ca2+ through the equilibrium of calcite dissolution-precipitation, and thus indirectly influence surface energy. Our results unveil the importance of fluid-rock interaction on subcritical crack growth and shed light on hydrocarbon exploitation and CO2 capture and storage in carbonate reservoirs. These findings also delineate the inner connection between geochemical and geo-mechanical properties at subsurface. (C) 2020 Published by Elsevier B.V.