On the spectroscopy of Bi3+ in d10 post-transition metal oxides

被引：31

作者：

Boutinaud, Philippe ^{[1
]}

机构：

[1] Clermont Univ Auvergne, SIGMA Clermont, Inst Chim Clermont Ferrand, BP 10448, F-63000 Clermont Ferrand, France

来源：

JOURNAL OF LUMINESCENCE | 2020年 / 223卷

关键词：

Bi3+; Charge transfer; d(10) post-transition metals; Oxide compounds; PERSISTENT LUMINESCENCE; ENERGY; ION; SN;

D O I：

10.1016/j.jlumin.2020.117219

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The optical spectroscopy of Bi3+ in d(10)-based post transition metal oxides (i. e. gallates, germanates, antimonates indates, stannates) is reviewed and analyzed in the frame of empirical models. 20 different compounds are examined. From this, a methodology is introduced to identify the preferred doping sites for Bi3+ and predict the intra- or extra-ionic origin of the Bi3+ emission in these systems. Further, the emission process in calcitestructured InBO3:Bi and GaBO3:Bi is reconsidered.

引用

页数：8

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