The Earth's surface bistatic reflectivity Gamma(LHCP,CyGNSS) is experimentally characterized using the novel Global Navigation Satellite Systems Reflectometry (GNSS-R) L -band passive multistatic radar technique from the Cyclone Global Navigation Satellite Systems (CyGNSS) eight-microsatellite constellation. The focus of this study is to evaluate the influence of the GNSS satellites' elevation angle theta(e) on Gamma(LHCP,cyGNss), as a function of soil moisture content (SMC) and effective surface roughness parameter h. As the average response, the change of the scattering regime at a global scale and considering also vegetated surfaces appears at theta(e) approximate to 55 degrees. This empirical observation is understood as a change on the dominant scattering term, from incoherent to coherent. Then, the correlation of Gamma(LHCP,CyGNSS) and SMC is evaluated as a function of theta(e) over specific sparsely vegetated target areas. The smoother the surface, the higher the angular variability of the Pearson correlation coefficients. Over croplands (e.g., Argentinian Pampas), an improved correlation coefficient is achieved over angular ranges where the coherent scattering regime becomes the dominant one. As such, this function depends on the surface roughness. The maximum correlation coefficients are found at different theta(e) for increasing mean roughness levels: r(pampas) approximate to 0.78 at theta(e) approximate to [60,70]degrees r(India) approximate to 0.72 at theta(e) approximate to [50,60]degrees, and r(Sudan) approximate to 0.74 at theta(e) [30,40]degrees. SMC retrieval algorithms based on GNSS-R multi -angular information could benefit from these findings, so as to improve the accuracy using single-polarized signals.