Metal-oxygen isopolyhedra assembled into fullerene topologies

被引：84

作者：

Forbes, Tori Z. ^{[1
]}

McAlpin, J. Gregory ^{[1
]}

Murphy, Rachel ^{[1
]}

Burns, Peter C. ^{[1
,2
,3
]}

机构：

[1] Univ Notre Dame, Dept Civil Engn & Geol Sci, Notre Dame, IN 46556 USA

[2] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

[3] Argonne Natl Lab, Div Chem Sci & Engn, Argonne, IL 60439 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 15期

关键词：

peroxide; polyoxometalates; self-assembly; solid-state structures; uranium;

D O I：

10.1002/anie.200705563

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conditions that permit the assembly of metal-oxygen isopolyhedra into fullerene topologies favor the hexagonal bipyramid as the basic building unit. Uranyl hexagonal bipyramids containing two peroxide edges have been used to create a cage cluster with a fullerene topology containing 50 polyhedra (see picture), as well as cage cluster of 40 polyhedra that contains topological squares, pentagons, and hexago. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2824 / 2827

页数：4

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