Manganese(I)-Catalyzed H-P Bond Activation via Metal-Ligand Cooperation

被引：63

作者：

Perez, Juana M. ^{[1
]}

Postolache, Roxana ^{[1
]}

Reis, Marta Castineira ^{[1
]}

Sinnema, Esther G. ^{[1
]}

Vargova, Denisa ^{[1
]}

de Vries, Folkert ^{[1
]}

Otten, Edwin ^{[1
]}

Ge, Luo ^{[1
]}

Harutyunyan, Syuzanna R. ^{[1
]}

机构：

[1] Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2021年 / 143卷 / 48期

基金：

欧洲研究理事会;

关键词：

ASYMMETRIC HYDROPHOSPHINATION; KETONES; HYDROGENATION; CATALYSIS; DESIGN;

D O I：

10.1021/jacs.1c10756

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report that chiral Mn(I) complexes are capable of H-P bond activation. This activation mode enables a general method for the hydrophosphination of internal and terminal alpha,beta-unsaturated nitriles. Metal-ligand cooperation, a strategy previously not considered for catalytic H-P bond activation, is at the base of the mechanistic action of the Mn(I)-based catalyst. Our computational studies support a stepwise mechanism for the hydrophosphination and provide insight into the origin of the enantioselectivity.

引用

页码：20071 / 20076

页数：6

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