Ln[N(SiMe3)2]3/RNH2 catalyzed monoaddition of terminal alkynes to nitriles:: A novel and concise access to the synthesis of ynones

被引：47

作者：

Shen, Quansheng ^{[1
]}

Huang, Wen ^{[1
]}

Wang, Jialiang ^{[1
]}

Zhou, Xigeng ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 02期

关键词：

D O I：

10.1021/om700891k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mild and highly selective Ln[N(SiMe3)(2)](3)/n-BuNH2 catalyzed addition of terminal alkynes to nitriles has been established, revealing a novel reactivity pattern of alkynes with nitriles and providing anew, economical, and mild method for the synthesis of conjugated ynones.

引用

收藏

页码：301 / 303

页数：3

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