Ln[N(SiMe3)2]3/RNH2 catalyzed monoaddition of terminal alkynes to nitriles:: A novel and concise access to the synthesis of ynones

被引：47
作者：
Shen, Quansheng [1 ]
Huang, Wen [1 ]
Wang, Jialiang [1 ]
Zhou, Xigeng [1 ,2 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ORGANOMETALLICS | 2008年 / 27卷 / 02期
关键词：
D O I：
10.1021/om700891k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A mild and highly selective Ln[N(SiMe3)(2)](3)/n-BuNH2 catalyzed addition of terminal alkynes to nitriles has been established, revealing a novel reactivity pattern of alkynes with nitriles and providing anew, economical, and mild method for the synthesis of conjugated ynones.
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收藏
页码：301 / 303
页数：3
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