Cloud point prediction of fuels and fuel blends

被引:38
作者
Mirante, FIC [1 ]
Coutinho, JAP [1 ]
机构
[1] Univ Aveiro, Dept Quim, P-3810193 Aveiro, Portugal
关键词
cloud point; fuel blends; n-alkane;
D O I
10.1016/S0378-3812(01)00352-1
中图分类号
O414.1 [热力学];
学科分类号
摘要
The cloud point temperature, the temperature at which the first wax crystals appear in solution, is one of the most important specifications associated with the low temperature behaviour of a fuel. A database of about 80 fuels and fuel blends was collected and used to assess the performance of the three predictive local composition models (Wilson, NRTL and UNIQUAC) for cloud point prediction. The results indicates that Predictive UNIQUAC can predict the cloud points of the fuels within the experimental uncertainty of the measurements. It could thus be a useful tool in the production of fuels both in the design of refining process and the blend of fuels to meet the low temperature specifications. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:247 / 255
页数:9
相关论文
共 28 条
[1]  
*ASTM, 1999, 97597 ASTM D
[2]   DIESEL FUELS - DETERMINATION OF ONSET CRYSTALLIZATION TEMPERATURE, POUR POINT AND FILTER PLUGGING POINT BY DIFFERENTIAL SCANNING CALORIMETRY - CORRELATION WITH STANDARD TEST METHODS [J].
CLAUDY, P ;
LETOFFE, JM ;
NEFF, B ;
DAMIN, B .
FUEL, 1986, 65 (06) :861-864
[3]   Predictive local composition models:: NRTL and UNIQUAC and their application to model solid-liquid equilibrium of n-alkanes [J].
Coutinho, JAP .
FLUID PHASE EQUILIBRIA, 1999, 158 :447-457
[4]   Experimental measurements and thermodynamic modeling of paraffinic wax formation in undercooled solutions [J].
Coutinho, JAP ;
RuffierMeray, V .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (11) :4977-4983
[5]   Predictive UNIQUAC: A new model for the description of multiphase solid-liquid equilibria in complex hydrocarbon mixtures [J].
Coutinho, JAP .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (12) :4870-4875
[6]   Measurements and modelling of wax formation in diesel fuels [J].
Coutinho, JAP ;
Dauphin, C ;
Daridon, JL .
FUEL, 2000, 79 (06) :607-616
[7]   A thermodynamic model for predicting wax formation in jet and diesel fuels [J].
Coutinho, JAP .
ENERGY & FUELS, 2000, 14 (03) :625-631
[8]   A local composition model for paraffinic solid solutions [J].
Coutinho, JAP ;
Knudsen, K ;
Andersen, SI ;
Stenby, EH .
CHEMICAL ENGINEERING SCIENCE, 1996, 51 (12) :3273-3282
[9]   Wax content measurements in partially frozen paraffinic systems [J].
Dauphin, C ;
Daridon, JL ;
Coutinho, JAP ;
Baylère, P ;
Potin-Gautier, M .
FLUID PHASE EQUILIBRIA, 1999, 161 (01) :135-151
[10]  
KHAN HU, 1990, OIL GAS J, V88, P98