Electrochemistry: Electrochemically generated superoxide ion in ionic liquids: Aapplications to green chemistry

被引：0

作者：

AlNashef, IM ^{[1
]}

Matthews, MA ^{[1
]}

Weidner, JW ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem Engn, Columbia, SC 29208 USA

来源：

IONIC LIQUIDS AS GREEN SOLVENTS: PROGRESS AND PROSPECTS | 2003年 / 856卷

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The superoxide ion, which can be electrochemically generated from oxygen in dry room temperature ionic liquids (RTILs), is a safe and mild oxidizing agent that has several potential applications. We have shown that the superoxide ion in RTIL can be used to destroy hexachlorobenzene (HCB), which represents a serious environmental problem. The electrochemically generated superoxide ion was also used to oxidize benzyl alcohol and benzhydrol to benzoic acid and benzophenone, respectively.

引用

页码：509 / 525

页数：17

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