Electrochemistry: Electrochemically generated superoxide ion in ionic liquids: Aapplications to green chemistry

被引：0
|
作者：
AlNashef, IM [1 ]
Matthews, MA [1 ]
Weidner, JW [1 ]
机构：
[1] Univ S Carolina, Dept Chem Engn, Columbia, SC 29208 USA
来源：
IONIC LIQUIDS AS GREEN SOLVENTS: PROGRESS AND PROSPECTS | 2003年 / 856卷
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D O I：
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The superoxide ion, which can be electrochemically generated from oxygen in dry room temperature ionic liquids (RTILs), is a safe and mild oxidizing agent that has several potential applications. We have shown that the superoxide ion in RTIL can be used to destroy hexachlorobenzene (HCB), which represents a serious environmental problem. The electrochemically generated superoxide ion was also used to oxidize benzyl alcohol and benzhydrol to benzoic acid and benzophenone, respectively.
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页码：509 / 525
页数：17
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