Iridium-Catalyzed Oxidative Methyl Esterification of Primary Alcohols and Diols with Methanol

被引：89
作者：
Yamamoto, Nobuyuki [1 ]
Obora, Yasushi [1 ]
Ishii, Yasutaka [1 ]
机构：
[1] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Osaka 5648680, Japan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 08期
关键词：
CARBOXYLIC-ACIDS; ESTERS; ALDEHYDES; EFFICIENT; TRANSFORMATION; DIMERIZATION; CONVERSION; DIOXIDE; TRIMETHYLSILYLDIAZOMETHANE; HYDROGENATION;
D O I：
10.1021/jo2003264
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Oxidative methyl esterification of primary alcohols and diols with methanol was successfully achieved, using acetone as a hydrogen acceptor, under the influence of an iridium complex combined with 2-(methylamino)ethanol (MAE) as catalyst.
引用
收藏
页码：2937 / 2941
页数：5
相关论文
共 50 条
  • [21] Covalently Bound Benzyl Ligand Promotes Selective Palladium-Catalyzed Oxidative Esterification of Aldehydes with Alcohols
    Liu, Chao
    Tang, Shan
    Zheng, Liwei
    Liu, Dong
    Zhang, Heng
    Lei, Aiwen
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (23) : 5662 - 5666
  • [22] General and Selective Palladium-Catalyzed Oxidative Esterification of Alcohols
    Gowrisankar, Saravanan
    Neumann, Helfried
    Beller, Matthias
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (22) : 5139 - 5143
  • [23] Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols Using MaxPHOX Ligands: Experimental and Theoretical Study
    Cabre, Albert
    Garcon, Marti
    Gallen, Albert
    Grisoni, Lorenzo
    Grabulosa, Arnald
    Verdaguer, Xavier
    Riera, Antoni
    CHEMCATCHEM, 2020, 12 (16) : 4112 - 4120
  • [24] Mechanochemical Palladium-Catalyzed Oxidative Esterification of Alcohols
    van Bonn, Pit
    Dressler, Daniela
    Weitenhagen, Fabian
    Bolm, Carsten
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2022, 10 (04): : 1361 - 1366
  • [25] Accessing para-Alkylphenols via Iridium-Catalyzed Site-Specific Deoxygenation of Alcohols
    Wang, Jing
    Wang, Tingting
    Du, Hongguang
    Chen, Ning
    Xu, Jiaxi
    Yang, Zhanhui
    JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (17) : 12572 - 12584
  • [26] Iridium-Catalyzed Intramolecular Oxidative Cyclization of Alkenyl Amides and Alkenoic Acids
    Nagamoto, Midori
    Nishimura, Takahiro
    Yorimitsu, Hideki
    SYNTHESIS-STUTTGART, 2017, 49 (18): : 4272 - 4282
  • [27] Iridium-Catalyzed 1,3-Hydrogen Shift/Chlorination of Allylic Alcohols
    Ahlsten, Nanna
    Gomez, Antonio Bermejo
    Martin-Matute, Belen
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (24) : 6273 - 6276
  • [28] Iridium-Catalyzed Domino Hydroformylation/Hydrogenation of Olefins to Alcohols: Synergy of Two Ligands
    Huang, Weiheng
    Tian, Xinxin
    Jiao, Haijun
    Jackstell, Ralf
    Beller, Matthias
    CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (09)
  • [29] Palladium-Catalyzed Aerobic Oxidative Cross-Esterification of Aldehydes with Alcohols
    Gao, Meng
    Chen, Meng
    Li, Yang
    Tang, Hong
    Ding, Hao
    Wang, Kai
    Yang, Lingen
    Li, Cuiting
    Lei, Aiwen
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 6 (11) : 1566 - 1568
  • [30] Iridium-Catalyzed Enantioconvergent Construction of Piperidines and Tetrahydroisoquinolines from Racemic 1,5-Diols
    Diao, Huanlin
    Liu, Kexin
    Yu, Rong
    Chen, Jilin
    Liu, Yongbing
    Yang, Bin-Miao
    Zhao, Yu
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 147 (01) : 610 - 618
12345