Iridium-Catalyzed Oxidative Methyl Esterification of Primary Alcohols and Diols with Methanol

被引:89
作者
Yamamoto, Nobuyuki [1 ]
Obora, Yasushi [1 ]
Ishii, Yasutaka [1 ]
机构
[1] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Osaka 5648680, Japan
关键词
CARBOXYLIC-ACIDS; ESTERS; ALDEHYDES; EFFICIENT; TRANSFORMATION; DIMERIZATION; CONVERSION; DIOXIDE; TRIMETHYLSILYLDIAZOMETHANE; HYDROGENATION;
D O I
10.1021/jo2003264
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Oxidative methyl esterification of primary alcohols and diols with methanol was successfully achieved, using acetone as a hydrogen acceptor, under the influence of an iridium complex combined with 2-(methylamino)ethanol (MAE) as catalyst.
引用
收藏
页码:2937 / 2941
页数:5
相关论文
共 50 条
  • [1] Iridium-Catalyzed Alkylation of Methylquinolines with Alcohols
    Obora, Yasushi
    Ogawa, Shinji
    Yamamoto, Nobuyuki
    JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (20) : 9429 - 9433
  • [2] Tuning the selectivity in iridium-catalyzed acceptorless dehydrogenative coupling of primary alcohols
    Tabasi, Nihal S.
    Genc, Sertac
    Gulcemal, Derya
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2022, 20 (33) : 6582 - 6592
  • [3] Iridium-Catalyzed Isomerization of Primary Allylic Alcohols
    Mantilli, Luca
    Mazet, Clement
    CHIMIA, 2009, 63 (1-2) : 35 - 37
  • [4] Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols
    Mantilli, Luca
    Gerard, David
    Torche, Sonya
    Besnard, Celine
    Mazet, Clement
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (28) : 5143 - 5147
  • [5] Iridium-catalyzed α-Alkylation of Acetonitrile with Primary and Secondary Alcohols
    Sawaguchi, Takuya
    Obora, Yasushi
    CHEMISTRY LETTERS, 2011, 40 (09) : 1055 - 1057
  • [6] Iridium-catalyzed oxidative dimerization of primary alcohols to esters using 2-butanone as an oxidant
    Suzuki, T
    Matsuo, T
    Watanabe, K
    Katoh, T
    SYNLETT, 2005, (09) : 1453 - 1455
  • [7] Relay Catalysis for Selective Aerobic Oxidative Esterification of Primary Alcohols with Methanol
    Yu, Yibo
    Lin, Jie
    Qin, Anni
    Wang, Huanan
    Wang, Jie
    Wang, Weiyi
    Wu, Guolin
    Zhang, Qian
    Qian, Hui
    Ma, Shengming
    ORGANIC LETTERS, 2024, 26 (16) : 3469 - 3474
  • [8] Iridium-Catalyzed C5-Regioselective Esterification of Dienyl Alcohols with Carboxylic Acids
    Chen, Jiadong
    Zhang, Yulu
    Tang, Shengbiao
    Shao, Ying
    Sun, Jiangtao
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 26 (32)
  • [9] Iridium-Catalyzed Selective Cross-Coupling of Ethylene Glycol and Methanol to Lactic Acid
    Wu, Jiajie
    Shen, Lingyun
    Chen, Zhe-Ning
    Zheng, Qingshu
    Xu, Xin
    Tu, Tao
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (26) : 10421 - 10425
  • [10] Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids
    Tang, Shengbiao
    Zhang, Peng
    Wang, Changkai
    Shao, Ying
    Sun, Jiangtao
    CHEMICAL COMMUNICATIONS, 2021, 57 (84) : 11080 - 11083