Alternative Demetalation Method for Cu(I)-Phenanthroline-Based Catenanes and Rotaxanes

被引：35

作者：

Megiatto, Jackson D., Jr. ^{[1
]}

Schuster, David I. ^{[1
]}

机构：

[1] NYU, Dept Chem, New York, NY 10003 USA

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 07期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

INTERLOCKED MACROCYCLIC LIGANDS; CONVERGENT SYNTHESIS; PHOTOINDUCED PROCESSES; COORDINATION-COMPOUNDS; TEMPLATED SYNTHESIS; COMPLEXES; PHOTOPHYSICS; METATHESIS; COPPER(I); PORPHYRIN;

D O I：

10.1021/ol200304d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and less hazardous procedure for demetalation of Cu(I)-phenanthroline-based interlocked molecules, using aqueous MOH rather than toxic KCN, has been developed. The conditions are compatible with materials containing nucleophile-sensitive appended groups such as C-60, and coordinating moieties such as zinc(II)-porphyrins.

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页码：1808 / 1811

页数：4

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