Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

被引：10
|
作者：
Scicluna, Todd R. [2 ]
Fraser, Benjamin H. [2 ]
Gorham, Nicole T. [4 ]
MacLellan, Jonathan G. [2 ]
Massi, Massimiliano [1 ]
Skelton, Brian W. [3 ]
St Pierre, Timothy G. [4 ]
Woodward, Robert C. [4 ]
机构：
[1] Curtin Univ Technol, Dept Chem, Perth, WA 6845, Australia
[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
[3] Univ Western Australia, Sch Biomed Biomol & Chem Sci, Crawley, WA 6009, Australia
[4] Univ Western Australia, Sch Phys, Crawley, WA 6009, Australia
来源：
CRYSTENGCOMM | 2010年 / 12卷 / 11期
基金：
澳大利亚研究理事会;
关键词：
COMPLEXES; METAL; LIGANDS;
D O I：
10.1039/c0ce00036a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl-2], the disubstituted [Co(H2L)(2)][PF6](2), and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [{Co(H2L)(2)}(H2L)(4)][PF6](2), as illustrated by X-ray crystal structure analysis.
引用
收藏
页码：3422 / 3424
页数：3
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