Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

被引：10

作者：

Scicluna, Todd R. ^{[2
]}

Fraser, Benjamin H. ^{[2
]}

Gorham, Nicole T. ^{[4
]}

MacLellan, Jonathan G. ^{[2
]}

Massi, Massimiliano ^{[1
]}

Skelton, Brian W. ^{[3
]}

St Pierre, Timothy G. ^{[4
]}

Woodward, Robert C. ^{[4
]}

机构：

[1] Curtin Univ Technol, Dept Chem, Perth, WA 6845, Australia

[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[3] Univ Western Australia, Sch Biomed Biomol & Chem Sci, Crawley, WA 6009, Australia

[4] Univ Western Australia, Sch Phys, Crawley, WA 6009, Australia

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 11期

基金：

澳大利亚研究理事会;

关键词：

COMPLEXES; METAL; LIGANDS;

D O I：

10.1039/c0ce00036a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl-2], the disubstituted [Co(H2L)(2)][PF6](2), and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [{Co(H2L)(2)}(H2L)(4)][PF6](2), as illustrated by X-ray crystal structure analysis.

引用

页码：3422 / 3424

页数：3

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