Tracking the progression of bronze disease - A synchrotron X-ray diffraction study of nantokite hydrolysis

被引：24

作者：

Grayburn, Rosie ^{[1
,2
]}

Dowsett, Mark ^{[1
]}

Hand, Matthew ^{[1
]}

Sabbe, Pieter-Jan ^{[2
]}

Thompson, Paul ^{[3
]}

Adriaens, Annemie ^{[2
]}

机构：

[1] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

[2] Univ Ghent, Dept Analyt Chem, B-9000 Ghent, Belgium

[3] XMaS ESRF, F-38043 Grenoble, France

来源：

CORROSION SCIENCE | 2015年 / 91卷

关键词：

Copper; XRD; ELECTROCHEMICAL CORROSION; COPPER; STABILIZATION;

D O I：

10.1016/j.corsci.2014.11.021

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The hydrolysis of nantokite to form cuprite could be a reaction step in the progression of bronze disease on cupreous objects d'art. In this paper, this transformation is visualized for the first time using a time-resolved synchrotron X-ray diffraction experiment. Complete conversion of nantokite to cuprite was observed on a nantokite patina over 5 h in water using time-resolved synchrotron X-ray diffraction. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：220 / 223

页数：4

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