Tracking the progression of bronze disease - A synchrotron X-ray diffraction study of nantokite hydrolysis

被引：24
作者：
Grayburn, Rosie [1 ,2 ]
Dowsett, Mark [1 ]
Hand, Matthew [1 ]
Sabbe, Pieter-Jan [2 ]
Thompson, Paul [3 ]
Adriaens, Annemie [2 ]
机构：
[1] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
[2] Univ Ghent, Dept Analyt Chem, B-9000 Ghent, Belgium
[3] XMaS ESRF, F-38043 Grenoble, France
来源：
CORROSION SCIENCE | 2015年 / 91卷
关键词：
Copper; XRD; ELECTROCHEMICAL CORROSION; COPPER; STABILIZATION;
D O I：
10.1016/j.corsci.2014.11.021
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The hydrolysis of nantokite to form cuprite could be a reaction step in the progression of bronze disease on cupreous objects d'art. In this paper, this transformation is visualized for the first time using a time-resolved synchrotron X-ray diffraction experiment. Complete conversion of nantokite to cuprite was observed on a nantokite patina over 5 h in water using time-resolved synchrotron X-ray diffraction. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：220 / 223
页数：4
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