Highly luminescent flexible amino-functionalized graphene quantum dots@cellulose nanofiber-clay hybrids for white-light emitting diodes

被引:74
作者
Tetsuka, H. [1 ]
Nagoya, A. [1 ]
Asahi, R. [1 ]
机构
[1] Toyota Cent Res & Dev Labs Inc, Frontier Res Ctr, Nagakute, Aichi 4801192, Japan
关键词
TOTAL-ENERGY CALCULATIONS; WAVE BASIS-SET; HEAT-RESISTANT; FILMS; EFFICIENT; COMPOSITE; OXIDE;
D O I
10.1039/c5tc00250h
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Amino-functionalized graphene quantum dots (afGQDs) made from graphene sheets glow bright with various colors under single-wavelength excitation, depending on their surface functional groups. These afGQDs were incorporated into a flexible and transparent clay host using electrostatic interactions between cellulose nanofiber (CNF) wrapped-afGQDs (CNF@afGQDs) and clay platelets. The resultant flexible afGQDs@CNF-clay films with a well-organized structure exhibited bright colorful photoluminescence, and were applied as a color converting material for blue light-emitting diodes (LEDs) to achieve white light emission. The af-GQDs@CNF-clay film based white LEDs showed pure white light emission with a CIE coordinate of (0.33, 0.37). The afGQDs@CNF-clay films with tunable emission are promising for use in future light emitting devices.
引用
收藏
页码:3536 / 3541
页数:6
相关论文
共 21 条
  • [1] Bonaccorso F, 2010, NAT PHOTONICS, V4, P611, DOI [10.1038/NPHOTON.2010.186, 10.1038/nphoton.2010.186]
  • [2] Flexible transparent clay films with heat-resistant and high gas-barrier properties
    Ebina, Takeo
    Mizukami, Fujio
    [J]. ADVANCED MATERIALS, 2007, 19 (18) : 2450 - +
  • [3] Luminscent Graphene Quantum Dots for Organic Photovoltaic Devices
    Gupta, Vinay
    Chaudhary, Neeraj
    Srivastava, Ritu
    Sharma, Gauri Datt
    Bhardwaj, Ramil
    Chand, Suresh
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (26) : 9960 - 9963
  • [4] Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
    Kresse, G
    Furthmuller, J
    [J]. PHYSICAL REVIEW B, 1996, 54 (16): : 11169 - 11186
  • [5] Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
    Kresse, G
    Furthmuller, J
    [J]. COMPUTATIONAL MATERIALS SCIENCE, 1996, 6 (01) : 15 - 50
  • [6] Electroluminescence from Graphene Quantum Dots Prepared by Amidative Cutting of Tattered Graphite
    Kwon, Woosung
    Kim, Young-Hoon
    Lee, Chang-Lyoul
    Lee, Minkyung
    Choi, Hee Cheul
    Lee, Tae-Woo
    Rhee, Shi-Woo
    [J]. NANO LETTERS, 2014, 14 (03) : 1306 - 1311
  • [7] An Electrochemical Avenue to Green-Luminescent Graphene Quantum Dots as Potential Electron-Acceptors for Photovoltaics
    Li, Yan
    Hu, Yue
    Zhao, Yang
    Shi, Gaoquan
    Deng, Lier
    Hou, Yanbing
    Qu, Liangti
    [J]. ADVANCED MATERIALS, 2011, 23 (06) : 776 - +
  • [8] Nitrogen-Doped Graphene Quantum Dots with Oxygen-Rich Functional Groups
    Li, Yan
    Zhao, Yang
    Cheng, Huhu
    Hu, Yue
    Shi, Gaoquan
    Dai, Liming
    Qu, Liangti
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (01) : 15 - 18
  • [9] Loh KP, 2010, NAT CHEM, V2, P1015, DOI [10.1038/nchem.907, 10.1038/NCHEM.907]
  • [10] An efficient and stable fluorescent graphene quantum dot-agar composite as a converting material in white light emitting diodes
    Luk, C. M.
    Tang, L. B.
    Zhang, W. F.
    Yu, S. F.
    Teng, K. S.
    Lau, S. P.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (42) : 22378 - 22381