The anation by oxalate and isomerization of cis- and trans-[Co(en)2(OH2)OH]2+

被引：2
|
作者：
Buckingham, DA
Clark, CR
Miskelly, GM
机构：
[1] Univ Otago, Dept Chem, Dunedin, New Zealand
[2] Univ Auckland, Auckland 1, New Zealand
来源：
INORGANIC CHEMISTRY | 2000年 / 39卷 / 26期
关键词：
D O I：
10.1021/ic000220d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Anation of cis- and trans-[Co(en)(2)(OH2)OH](2+) by C2O42- in the pH range 6-9 occurs via the ion pairs cis- and trans-[Co(en)(2)(OH2)OH](2+).C2O42-, and both cis- and trans- ion pairs lead to both cis-and trans[Co(en)(2)(OC2O3)OH2](+) Competing isomerization of the reactants occurs both in the free ions and in the ion-pairs.
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页码：6139 / +
页数：4
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