Inkjet Printing of Microporous Silica Gas Separation Membranes

被引:5
作者
Bram, Martin [1 ]
Dornseiffer, Juergen [1 ]
Hoffmann, Jan [1 ]
van Gestel, Tim [1 ]
Meulenberg, Wilhelm A. [1 ]
Stoever, Detlev [1 ]
机构
[1] Forschungszentrum Julich, Inst Energy & Climate Res Mat Synth & Proc IEK 1, D-52425 Julich, Germany
关键词
HYDROTHERMAL STABILITY; CATALYST LAYERS;
D O I
10.1111/jace.13657
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Inkjet printing was applied to manufacture silica-based gas separation membranes, which were coated on a pore-graduated alumina substrate with a mesoporous -alumina interlayer. A silica sol diluted by 1-propanol was used to print the membrane layer followed by thermal treatment in a rapid thermal processing furnace. The membrane thickness was varied between 30 and 110nm by conducting one, two, and three coating steps. In the latter case, H-2 permeance in the range of 2.0x10(-8)-3.3x10(-8)mol/s.m(2) .Pa combined with H-2/CO2 selectivities in the range of 15-25 were achieved, proving the concept that inorganic gas separation membranes can be successfully processed by inkjet printing.
引用
收藏
页码:2388 / 2394
页数:7
相关论文
共 29 条
[1]   Inkjet printing of photocatalytically active TiO2 thin films from water based precursor solutions [J].
Arin, Melis ;
Lommens, Petra ;
Avci, Nursen ;
Hopkins, Simon C. ;
De Buysser, Klaartje ;
Arabatzis, Ioannis M. ;
Fasaki, Ioanna ;
Poelman, Dirk ;
Van Driessche, Isabel .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2011, 31 (06) :1067-1074
[2]  
Atkinson A, 1997, J SOL-GEL SCI TECHN, V8, P1093
[3]   Fabrication and testing of a planar microstructured concept module with integrated palladium membranes [J].
Boeltken, T. ;
Belimov, M. ;
Pfeifer, P. ;
Peters, T. A. ;
Bredesen, R. ;
Dittmeyer, R. .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2013, 67 :136-147
[4]   Hydrothermal stability of microporous silica and niobia-silica membranes [J].
Boffa, V. ;
Blank, D. H. A. ;
ten Elshof, J. E. .
JOURNAL OF MEMBRANE SCIENCE, 2008, 319 (1-2) :256-263
[5]  
Brinker C.J., 2013, Sol-gel science: the physics and chemistry of sol-gel processing, DOI 10.1016/C2009-0-22386-5
[6]  
Burggraf A. J., 1996, FUNDAMENTALS INORGAN
[7]   Inkjet printing for materials and devices [J].
Calvert, P .
CHEMISTRY OF MATERIALS, 2001, 13 (10) :3299-3305
[8]   Catalytic reactors based on porous ceramic membranes [J].
Coronas, J ;
Santamaría, J .
CATALYSIS TODAY, 1999, 51 (3-4) :377-389
[9]   Improved performance of silica membranes for gas separation [J].
de Vos, RM ;
Verweij, H .
JOURNAL OF MEMBRANE SCIENCE, 1998, 143 (1-2) :37-51
[10]   PERMEATION AND SEPARATION STUDIES ON MICROPOROUS SOL-GEL MODIFIED CERAMIC MEMBRANES [J].
DELANGE, RSA ;
HEKKINK, JHA ;
KEIZER, K ;
BURGGRAAF, AJ .
MICROPOROUS MATERIALS, 1995, 4 (2-3) :169-186