Cyclometalated ruthenium(II) complexes with a bis-carbene CCC-pincer ligand

被引：38
|
作者：
Zhang, You-Ming [1 ,2 ]
Shao, Jiang-Yang [1 ]
Yao, Chang-Jiang [1 ]
Zhong, Yu-Wu [1 ,3 ]
机构：
[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 31期
基金：
中国国家自然科学基金;
关键词：
HETEROCYCLIC CARBENES; RU(II) COMPLEXES; 1,2,4,5-TETRA(2-PYRIDYL)BENZENE; NONINNOCENT; FILMS; DFT;
D O I：
10.1039/c2dt31015e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4'-di-p-anisylamino-2,2':6',2 ''-terpyridine is presented. The Ru-II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.
引用
收藏
页码：9280 / 9282
页数：3
相关论文
共 50 条
  • [41] Fischer Dinuclear and Mononuclear Bis-Carbene Complexes of Thiophene and Thiophene Derivatives
    Lotz, Simon
    van Jaarsveld, Nina A.
    Liles, David C.
    Crause, Chantelle
    Goerls, Helmar
    Terblans, Yvette M.
    ORGANOMETALLICS, 2012, 31 (15) : 5371 - 5383
  • [42] First chelated chiral N-Heterocyclic bis-carbene complexes
    Clyne, DS
    Jin, J
    Genest, E
    Gallucci, JC
    RajanBabu, TV
    ORGANIC LETTERS, 2000, 2 (08) : 1125 - 1128
  • [43] Experimental and theoretical investigations of cyclometalated ruthenium(ii) complex containing CCC-pincer and anti-inflammatory drugs as ligands: synthesis, characterization, inhibition of cyclooxygenase and in vitro cytotoxicity activities in various cancer cell lines
    Tabrizi, Leila
    Olasunkanmi, Lukman O.
    Fadare, Olatomide A.
    DALTON TRANSACTIONS, 2019, 48 (02) : 728 - 740
  • [44] Carbocyclic pincer carbene complexes of ruthenium: syntheses and reversible hydrogenation
    Wiedmaier, Nicholas R.
    Schubert, Hartmut
    Mayer, Hermann A.
    Wesemann, Lars
    DALTON TRANSACTIONS, 2021, 50 (34) : 11814 - 11820
  • [45] Ruthenium complexes with an N-heterocyclic carbene NNC-pincer ligand: preparation and catalytic properties
    Mejuto, Carmen
    Garcia-Eleno, Marco A.
    Guisado-Barrios, Gregorio
    Spasyuk, Denis
    Gusev, Dmitri
    Peris, Eduardo
    Organic Chemistry Frontiers, 2015, 2 (08): : 936 - 941
  • [46] Stable N-functionalised 'pincer' bis carbene ligands and their ruthenium complexes; synthesis and catalytic studies
    Danopoulos, AA
    Winston, S
    Motherwell, WB
    CHEMICAL COMMUNICATIONS, 2002, (13) : 1376 - 1377
  • [47] Synthesis and characterization of a dicationic dihydrogen complex of iridium with a bis-carbene ligand set
    Vogt, M
    Pons, V
    Heinekey, DM
    ORGANOMETALLICS, 2005, 24 (08) : 1832 - 1836
  • [48] Di-tungsten bis-carbene complexes linked by condensed heteroaromatic spacers
    Lotz, Simon
    Landman, Marilé
    Görls, Helmar
    Crause, Chantelle
    Nienaber, Hubert
    Olivier, Andrew
    Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2007, 62 (03): : 419 - 426
  • [49] Mechanism of the oxidative addition of aryl halides to bis-carbene palladium(0) complexes
    Jutand, Anny
    Pytkowicz, Julien
    Roland, Sylvain
    Mangeney, Pierre
    PURE AND APPLIED CHEMISTRY, 2010, 82 (07) : 1393 - 1402
  • [50] The trans influence of the pyridine ligand on ruthenium(II)-porphyrin-carbene complexes
    Harada, T
    Wada, S
    Yuge, H
    Miyamoto, TK
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 : M37 - M39
12345