Cyclometalated ruthenium(II) complexes with a bis-carbene CCC-pincer ligand

被引：38
|
作者：
Zhang, You-Ming [1 ,2 ]
Shao, Jiang-Yang [1 ]
Yao, Chang-Jiang [1 ]
Zhong, Yu-Wu [1 ,3 ]
机构：
[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 31期
基金：
中国国家自然科学基金;
关键词：
HETEROCYCLIC CARBENES; RU(II) COMPLEXES; 1,2,4,5-TETRA(2-PYRIDYL)BENZENE; NONINNOCENT; FILMS; DFT;
D O I：
10.1039/c2dt31015e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4'-di-p-anisylamino-2,2':6',2 ''-terpyridine is presented. The Ru-II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.
引用
收藏
页码：9280 / 9282
页数：3
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