RuCo bimetallic alloy nanoparticles immobilized on multi-porous MIL-53(Al) as a highly efficient catalyst for the hydrolytic reaction of ammonia borane

被引：42

作者：

Chen Menghuan ^{[1
]}

Zhou, Liqun ^{[1
]}

Lu Di ^{[1
]}

Li Yue ^{[1
]}

Ning Honghui ^{[1
]}

Pan Yaxi ^{[1
]}

Xu Hongkun ^{[1
]}

Peng Weiwei ^{[1
]}

Zhang Shuren ^{[1
]}

机构：

[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Key Lab Synth & Applicat Organ Funct Mol, Coll Chem & Chem Engn,Minist Educ, Wuhan 430062, Hubei, Peoples R China

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2018年 / 43卷 / 03期

关键词：

RuCo alloy NPs; MIL-53(Al); Synergistic catalysis; Ammonia borane; Hydrogen release; METAL-ORGANIC FRAMEWORKS; HYDROGEN GENERATION; REUSABLE CATALYST; DOPED CARBON; EVOLUTION; DEHYDROGENATION; HYDRAZINE; CO; METHANOLYSIS; ADSORPTION;

D O I：

10.1016/j.ijhydene.2017.11.160

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Well-dispersed bimetallic RuCo alloy nanoparticles (NPs) were successfully immobilized on the multi-porous, water-tolerant metal organic frameworks MIL-53(Al) by a facile solvent impregnation method. Among the RuCo@MIL-53(Al) with different Ru/Co molar ratios, the Ru1Co1@MIL-53(Al) performed better and was superior to Ru@MIL-53(Al) and single RuCo NPs for the hydrolysis of ammonia borane (AB, NH3BH3), owing to the synergistic effect caused by the electronic and geometric interactions between Ru and Co atoms and bifunctional effect generated between the RuCo NPs and the MIL-53(Al) support. Compared with bimetallic Ru1Ni1 and Ru1Cu1 counterparts loadings, the Ru1Co1@MIL-53(A1) also showed better catalytic activity for the hydrolysis of AB. Moreover, the Ru1Co1@ MIL-53(Al) presented good durability and reusability in the catalytic reaction, and the activation energy (Ea) and turnover frequency values (TOF) were 34.32 kJ mol(-1) and 87.24 mol H-2 min(-1) (mol Ru)(-1), respectively. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：1439 / 1450

页数：12

共 60 条

[1] Synthesis, characterization, and CO2 adsorption of three metal-organic frameworks (MOFs): MIL-53, MIL-96, and amino-MIL-53 [J].