Microwave-assisted synthesis of 6-amino-β-cyclodextrins

被引：16

作者：

Puglisi, Antonino ^{[1
]}

Spencer, John ^{[1
]}

Clarke, James ^{[2
]}

Milton, John ^{[2
]}

机构：

[1] Univ Greenwich Medway, Sch Sci, Chatham ME4 4TB, Kent, England

[2] Oxford Nanopore Technol Ltd, Oxford OX4 4GA, England

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2012年 / 73卷 / 1-4期

关键词：

Microwave-assisted synthesis; 6-amino-beta-cyclodextrins; Functionalised cyclodextrins; Mono-pendant cyclodextrins; FUNCTIONALIZED BETA-CYCLODEXTRINS; MOLECULAR RECOGNITION; COPPER(II) COMPLEXES; AMINO-ACIDS; COORDINATION PROPERTIES; L-TRYPTOPHAN; DERIVATIVES; ENANTIOSELECTIVITY; THERMODYNAMICS; CATALYSIS;

D O I：

10.1007/s10847-011-0054-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general microwave-assisted procedure for the synthesis of 6-amino-beta-cyclodextrins is reported. Mono-tosyl-beta-cyclodextrin was used as the starting material in a one-pot route employing a solvent-free microwave-assisted reaction with a liquid amine. Shorter reaction times were observed for the formation of 6-amino-beta-cyclodextrins using this novel microwave approach compared to the thermal procedure.

引用

页码：475 / 478

页数：4

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