Transition Metal Nanoparticle Catalysis in Ionic Liquids

被引：300
作者：
Scholten, Jackson D. [1 ]
Leal, Barbara Caroline [1 ]
Dupont, Jairton [1 ]
机构：
[1] Univ Fed Rio Grande do Sul, Lab Mol Catalysis, Inst Chem, BR-91501970 Porto Alegre, RS, Brazil
来源：
ACS CATALYSIS | 2012年 / 2卷 / 01期
关键词：
ionic liquids; nanoparticles; catalysis; supramolecular chemistry; imidazolium salts; CROSS-COUPLING REACTIONS; STABILIZED PALLADIUM NANOPARTICLES; MOLTEN TETRABUTYLAMMONIUM BROMIDE; RUTHENIUM NANOCLUSTER CATALYST; ARENE HYDROGENATION CATALYSTS; SIZE-DEPENDENT FORMATION; N-DONOR LIGANDS; HECK REACTION; ROOM-TEMPERATURE; PD NANOPARTICLES;
D O I：
10.1021/cs200525e
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The main "molecular" physicochemical aspects involved in the catalytic applications of "soluble" transition metal nanoparticles in ionic liquids are used to explain their properties. In particular, a special view on the concepts of coordination catalysis is used to describe the properties of these nanoscale catalysts in solution as well as their scope and limitations in multiphase catalysis.
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收藏
页码：184 / 200
页数：17
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