Transition Metal Nanoparticle Catalysis in Ionic Liquids

被引：300

作者：

Scholten, Jackson D. ^{[1
]}

Leal, Barbara Caroline ^{[1
]}

Dupont, Jairton ^{[1
]}

机构：

[1] Univ Fed Rio Grande do Sul, Lab Mol Catalysis, Inst Chem, BR-91501970 Porto Alegre, RS, Brazil

来源：

ACS CATALYSIS | 2012年 / 2卷 / 01期

关键词：

ionic liquids; nanoparticles; catalysis; supramolecular chemistry; imidazolium salts; CROSS-COUPLING REACTIONS; STABILIZED PALLADIUM NANOPARTICLES; MOLTEN TETRABUTYLAMMONIUM BROMIDE; RUTHENIUM NANOCLUSTER CATALYST; ARENE HYDROGENATION CATALYSTS; SIZE-DEPENDENT FORMATION; N-DONOR LIGANDS; HECK REACTION; ROOM-TEMPERATURE; PD NANOPARTICLES;

D O I：

10.1021/cs200525e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The main "molecular" physicochemical aspects involved in the catalytic applications of "soluble" transition metal nanoparticles in ionic liquids are used to explain their properties. In particular, a special view on the concepts of coordination catalysis is used to describe the properties of these nanoscale catalysts in solution as well as their scope and limitations in multiphase catalysis.

引用

页码：184 / 200

页数：17

共 194 条

[31] Ionophilic phosphines: Versatile ligands for ionic liquid biphasic catalysis [J].

Consorti, Crestina S. ;

Aydos, Guilherme L. P. ;

Ebeling, Gunter ;

Dupont, Jaiertton .

ORGANIC LETTERS, 2008, 10 (02) :237-240

[32] Kinetics and mechanistic aspects of the Heck reaction promoted by a CN-palladacycle [J].

Consorti, CS ;

Flores, FR ;

Dupont, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (34) :12054-12065

[33] Charge-tagged N-heterocyclic carbenes [J].

Corilo, Yuri E. ;

Nachtigall, Fabiane M. ;

Abdelnur, Patricia V. ;

Ebeling, Gunter ;

Dupont, Jairton ;

Eberlin, Marcos N. .

RSC ADVANCES, 2011, 1 (01) :73-78

[34] Comparison between polyethylenglycol and imidazolium ionic liquids as solvents for developing a homogeneous and reusable palladium catalytic system for the Suzuki and Sonogashira coupling [J].

Corma, A ;

García, H ;

Leyva, A .

TETRAHEDRON, 2005, 61 (41) :9848-9854

[35] IRIDIUM COMPOUNDS IN CATALYSIS [J].

CRABTREE, R .

ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (09) :331-338

[36] Nitrile-functionalized pyrrolidinium ionic liquids as solvents for cross-coupling reactions involving in situ generated nanoparticle catalyst reservoirs [J].

Cui, Yugang ;

Biondi, Ilaria ;

Chaubey, Manish ;

Yang, Xue ;

Fei, Zhaofu ;

Scopelliti, Rosario ;

Hartinger, Christian G. ;

Li, Yongdan ;

Chiappe, Cinzia ;

Dyson, Paul J. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (08) :1834-1841

[37] Bimetallic PdAu nanoparticles as hydrogenation catalysts in imidazolium ionic liquids [J].

Dash, Priyabrat ;

Dehm, Nicole A. ;

Scott, Robert W. J. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 286 (1-2) :114-119

[38] 1-Methylimidazole stabilization of gold nanoparticles in imidazolium ionic liquids [J].

Dash, Priyabrat ;

Scott, Robert W. J. .

CHEMICAL COMMUNICATIONS, 2009, (07) :812-814

[39] N-Donor ligands based on bipyridine and ionic liquids: an efficient partnership to stabilize rhodium colloids. Focus on oxygen-containing compounds hydrogenation [J].

Denicourt-Nowicki, Audrey ;

Leger, Bastien ;

Roucoux, Alain .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (30) :13510-13517

[40] Ultrasound promoted C-C bond formation: Heck reaction at ambient conditions in room temperature ionic liquids [J].

Deshmukh, RR ;

Rajagopal, R ;

Srinivasan, KV .

CHEMICAL COMMUNICATIONS, 2001, (17) :1544-1545

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