Transition Metal Nanoparticle Catalysis in Ionic Liquids

被引：300
作者：
Scholten, Jackson D. [1 ]
Leal, Barbara Caroline [1 ]
Dupont, Jairton [1 ]
机构：
[1] Univ Fed Rio Grande do Sul, Lab Mol Catalysis, Inst Chem, BR-91501970 Porto Alegre, RS, Brazil
来源：
ACS CATALYSIS | 2012年 / 2卷 / 01期
关键词：
ionic liquids; nanoparticles; catalysis; supramolecular chemistry; imidazolium salts; CROSS-COUPLING REACTIONS; STABILIZED PALLADIUM NANOPARTICLES; MOLTEN TETRABUTYLAMMONIUM BROMIDE; RUTHENIUM NANOCLUSTER CATALYST; ARENE HYDROGENATION CATALYSTS; SIZE-DEPENDENT FORMATION; N-DONOR LIGANDS; HECK REACTION; ROOM-TEMPERATURE; PD NANOPARTICLES;
D O I：
10.1021/cs200525e
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The main "molecular" physicochemical aspects involved in the catalytic applications of "soluble" transition metal nanoparticles in ionic liquids are used to explain their properties. In particular, a special view on the concepts of coordination catalysis is used to describe the properties of these nanoscale catalysts in solution as well as their scope and limitations in multiphase catalysis.
引用
收藏
页码：184 / 200
页数：17
相关论文
共 194 条
[1]   Platinum nanoparticles supported on ionic liquid-modified magnetic nanoparticles: Selective hydrogenation catalysts [J].
Abu-Reziq, Raed ;
Wang, Dashan ;
Post, Michael ;
Alper, Howard .
ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (13) :2145-2150
[2]   Solubility of CO2,CH4, C2H6, C2H4, O2, and N2 in 1-hexyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide:: Comparison to other ionic liquids [J].
Anderson, Jessica L. ;
Dixon, Janeille K. ;
Brennecke, Joan F. .
ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (11) :1208-1216
[3]   Measurement of SO2 solubility in ionic liquids [J].
Anderson, Jessica L. ;
Dixon, JaNeille K. ;
Maginn, Edward J. ;
Brennecke, Joan F. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (31) :15059-15062
[4]  
Anthony JL, 2005, J PHYS CHEM B, V109, P6366, DOI 10.1021/jp0464041
[5]  
Astruc D., 2008, NANOPARTICLES CATALY
[6]   HETEROGENEOUS CATALYSIS IN ORGANIC-CHEMISTRY .10. EFFECT OF THE CATALYST SUPPORT ON THE REGIOCHEMISTRY OF THE HECK ARYLATION REACTION [J].
AUGUSTINE, RL ;
OLEARY, ST .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 95 (03) :277-285
[7]   Pd nanoparticles for C-C coupling reactions [J].
Balanta, Angelica ;
Godard, Cyril ;
Claver, Carmen .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (10) :4973-4985
[8]   The Heck Reaction in Ionic Liquids: Progress and Challenges [J].
Bellina, Fabio ;
Chiappe, Cinzia .
MOLECULES, 2010, 15 (04) :2211-2245
[9]   Ionic liquid-phase asymmetric catalytic hydrogenation: hydrogen concentration effects on enantioselectivity [J].
Berger, A ;
de Souza, RF ;
Delgado, MR ;
Dupont, J .
TETRAHEDRON-ASYMMETRY, 2001, 12 (13) :1825-1828
[10]   Probing the chemical interaction between iridium nanoparticles and ionic liquid by XPS analysis [J].
Bernardi, F. ;
Scholten, J. D. ;
Fecher, G. H. ;
Dupont, J. ;
Morais, J. .
CHEMICAL PHYSICS LETTERS, 2009, 479 (1-3) :113-116
12345678910