Rasta resin as support for TBD in base-catalyzed organic processes

被引：35

作者：

Bonollo, Simona ^{[1
]}

Lanari, Daniela ^{[1
]}

Angelini, Tommaso ^{[1
]}

Pizzo, Ferdinando ^{[1
]}

Marrocchi, Assunta ^{[1
]}

Vaccaro, Luigi ^{[1
]}

机构：

[1] Univ Perugia, Dipartimento Chim, CEMIN, Lab Green Synthet Organ Chem, I-06100 Perugia, Italy

来源：

JOURNAL OF CATALYSIS | 2012年 / 285卷 / 01期

关键词：

Heterogeneous catalysis; Solvent-free conditions; 1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD); Polymer-supported organocatalysts; CONJUGATE ADDITION; REUSABLE CATALYST; RADICAL POLYMERIZATION; RECYCLABLE CATALYST; GREEN CHEMISTRY; EFFICIENT; NITROALKANES; IMMOBILIZATION; THIOLYSIS; EPOXIDES;

D O I：

10.1016/j.jcat.2011.09.032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Although its intriguing features, such as uniform functionalization through the entire beads and a very high-loading capacity are suitable candidates for solid-phase synthesis and reagent-scavenging, the use of Rasta resin as support for organocatalysis has been little explored. In this contribution, Rasta polymer has been used to preparation of high-loading Rasta-TBD. This catalyst has been able to efficiently promote several organic transformations with constantly good and promising results. (C) 2011 Elsevier Inc. All rights reserved.

引用

页码：216 / 222

页数：7

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