Synthesis and Crystal Structures of [K(H2O)(Piv)]∞ and [K2(Phen)(H2O)2(Piv)2]∞

被引：5

作者：

Tsymbarenko, D. M. ^{[1
]}

Bukhtoyarova, E. A. ^{[1
]}

Korsakov, I. E. ^{[1
]}

Troyanov, S. I. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Moscow, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 37卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

MOLECULAR-STRUCTURE; COMPLEXES; CALCIUM; ALKALI; FILMS;

D O I：

10.1134/S1070328411100125

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A method for the synthesis of potassium pivalates (trimethylacetates) from potassium tert-butoxide and pivalic acid was proposed. The complexes of the formulas [K(H2O)(Piv)]8(I) and [K-2(Phen)(H2O)(2)(Piv)(2)](infinity) (II) (Piv denotes the pivalate anion and Phen denotes 1,10-phenanthroline) were obtained and characterized by elemental analysis and IR and H-1 NMR spectroscopy. The crystal structures of complexes I and II were determined using X-ray diffraction. Crystal structure I has a layered motif with two nonequivalent K atoms (C.N.s 5 + 2 and 6). The coordination of phenanthroline in II gives rise to a ribbon motif, the structure containing three nonequivalent K atoms (C.N.s 6, 6 + 1, and 8). DOI: 10.1134/S1070328411100125

引用

页码：825 / 831

页数：7

共 50 条

[21] Syntheses, crystal structures and characterization of two zeotype crystals of K4[Cr3O(H2O)3(OOCH)6]2[P2W18O62] • 9.5H2O and K4[Cr3O(H2O)3(OOCH)6] • [H3P2W17Co(H2O)O61] • 20H2O
Zhang Xin
You Wan-sheng
Zhu Zai-ming
Dang Li-qin
Sun Zhen-gang
Zheng Xue-fang
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2007, 23 (01) : 8 - 13
[22] Synthesis and crystal structures of supramolecular compounds: [Cu(mpca)2(H2O)] • 3H2O and [Cu2(mpca)2(pyr)4]
Hu, Fei-Long
Yin, Xian-Hong
Mi, Yan
Zhuang, Yue
Zhang, Shan-Shan
Huang, Zhong-Jing
JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (22) : 3613 - 3620
[23] Thermal Decomposition of [Cu(H2O)2(C8H4O4)], [CuNi(H2O)4(C8H4O4)2], and [Ni(H2O)2(C8H4O4)2](H2O)2 with the Formation of Metal and Bimetal Nanoparticles
Yudanova, L., I
Ishchenko, A., V
Rudina, N. A.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2021, 95 (08) : 1663 - 1670
[24] Synthesis and Structure of Heptaaqua{nitrilotris(methylenephosphonato)}(dibarium)sodium Monohydrate [Na(H2O)3{μ6-NH(CH2PO3)3}(μ-H2O)3Ba2(H2O)] • H2O
Somov, N. V.
Chausov, F. F.
Zakirova, R. M.
CRYSTALLOGRAPHY REPORTS, 2017, 62 (02) : 232 - 237
[25] Reversible Photochromic Properties of Ti2O3(H2O)2(C2O4) . H2O Material
Hu, Kangkai
Lei, E.
Zhao, Dan
Guo, Zhengang
Zhang, Bo
CHEMNANOMAT, 2022, 8 (01)
[26] Synthesis and Crystal Structure of Porous Zinc(II) Coordination Polymer {[Zn(L)2(H2O)2]•H2O}n Constructed by Isonicotinoylhydrazone Ligand
Chen Yan-Min
Xie Qing-Fan
Wei Zan-Bin
Chen Ling-Lan
Liu Jin-Hua
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2014, 30 (06) : 1243 - 1249
[27] Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions
Panagiotidis, Kosta
Glaum, Robert
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : I18 - U131
[28] Synthesis, thermal properties and photoisomerization of trans-[Ru(NO)Py2Cl2(H2O)]H2PO4•H2O
Makhinya, Alexander N.
Korolkov, Ilya V.
Il'in, Maxim A.
Baidina, Iraida A.
Plusnin, Pavel E.
Maximovski, Eugeni A.
Beletskaya, Elizaveta A.
Alferova, Nina I.
JOURNAL OF CHEMICAL SCIENCES, 2017, 129 (04) : 441 - 448
[29] Crystal structures of [Cu2(2,2′-bipyridine-N,N′)2(H2O)2(μ2-OH)2] (barbiturate)2•2H2O and [Cu(2,2′-bipyridine-N,N′)(H2O)(barbiturate-O)Cl]•2H2O
Golovnev, Nicolay N.
Molokeev, Maxim S.
Sterkhova, Irina V.
Lesnikov, Maxim K.
INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 97 : 88 - 92
[30] Hydrothermal Synthesis and Crystal Structure of a Novel Supramolecular Coordination Polymer {[Cu (bpdc) (H2O)] 2•2H2O}
Li, Li
Zhu, Lu
Qiao, Yongzhen
Yue, Zhongcheng
Zhang, Wenli
Niu, Yunyin
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2013, 43 (08) : 1007 - 1012

← 1 2 3 4 5 →