Synthesis of meso-tetrakis(imidazol-5-yl)porphyrins

被引：5
作者：
Amaravathi, M
Murthy, KSK
Rao, MK
Reddy, BS [1 ]
机构：
[1] Reg Engn Coll, Dept Chem, Warangal 506004, Andhra Pradesh, India
[2] Suven Pharmaceut Ltd, Hyderabad, Andhra Pradesh, India
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 38期
关键词：
D O I：
10.1016/S0040-4039(01)01216-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
meso-Tetrakis(imidazol-5-yl)porphyrins (TIP) have been prepared from 2-n-butylimidazole-5-carboxaldehyde and pyrrole in refluxing propionic acid. Different substituted imidazole aldehydes with a free NH group are synthesized and treated with pyrrole to afford the corresponding meso-tetrakis(2-n-butyl-(4-X)-imidazol-5-yl)porphyrins (X=Cl, Br or H). (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6745 / 6747
页数：3
相关论文
共 11 条
  • [1] PORPHYRIN SPONGES - INVERSION DISORDER AND INVERSION TWINNING IN LATTICE CLATHRATES BASED ON 5-COORDINATE METALLOTETRAARYLPORPHYRIN COMPLEXES
    BYRN, MP
    STROUSE, CE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) : 2501 - 2508
  • [2] PORPHYRIN SPONGES - STRUCTURAL SYSTEMATICS OF THE HOST LATTICE
    BYRN, MP
    CURTIS, CJ
    GOLDBERG, I
    HSIOU, Y
    KHAN, SI
    SAWIN, PA
    TENDICK, SK
    STROUSE, CE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (17) : 6549 - 6557
  • [3] STERIC EFFECTS ON ATROPISOMERISM IN TETRAARYLPORPHYRINS
    CROSSLEY, MJ
    FIELD, LD
    FORSTER, AJ
    HARDING, MM
    STERNHELL, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (02) : 341 - 348
  • [4] HUANG S, 1987, CHINESE J ORG CHEM, V3, P189
  • [5] SUPRAMOLECULAR ORGANIZATION OF IMIDAZOLYL-PORPHYRIN TO A SLIPPED COFACIAL DIMER
    KOBUKE, Y
    MIYAJI, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (09) : 4111 - 4112
  • [6] PORPHYRIN CHEMISTRY PERTAINING TO THE DESIGN OF ANTICANCER DRUGS .1. THE SYNTHESIS OF PORPHYRINS CONTAINING MESO-PYRIDYL AND MESO-SUBSTITUTED PHENYL FUNCTIONAL-GROUPS
    MENG, GZG
    JAMES, BR
    SKOV, KA
    [J]. CANADIAN JOURNAL OF CHEMISTRY, 1994, 72 (09) : 1894 - 1909
  • [7] MILGROM LR, 1991, J MOL ELECTRON, V7, P95
  • [8] 5,10,15,20-tetrakis(N-protected-imidazol-2-yl)porphyrins.
    Milgrom, LR
    Dempsey, PJF
    Yahioglu, G
    [J]. TETRAHEDRON, 1996, 52 (29) : 9877 - 9890
  • [9] MILGROM LR, 1994, TETRAHEDRON, V50, P13477
  • [10] A PRACTICAL SYNTHESIS OF 2-BUTYL-4(5)-CHLORO-5(4)-HYDROXYMETHYL-1H-IMIDAZOLE
    SHI, YJ
    FREY, LF
    TSCHAEN, DM
    VERHOEVEN, TR
    [J]. SYNTHETIC COMMUNICATIONS, 1993, 23 (18) : 2623 - 2630
12