ITO-free inverted organic solar cells fabricated with transparent and low resistance ZnO/Ag/ZnO multilayer electrode

被引:16
作者
Kim, Jun Ho [1 ]
Kang, Tae-Woon [2 ,3 ]
Na, Seok-In [2 ,3 ]
Yoo, Young-Zo [4 ]
Seong, Tae-Yeon [1 ]
机构
[1] Korea Univ, Dept Mat Sci & Engn, Seoul 136713, South Korea
[2] Chonbuk Natl Univ, Profess Grad Sch Flexible & Printable Elect, Jeonju 561756, Jeollabuk Do, South Korea
[3] Chonbuk Natl Univ, Polymer Mat Fus Res Ctr, Jeonju 561756, Jeollabuk Do, South Korea
[4] Duksan Hi Met Co Ltd, Ulsan 683804, South Korea
关键词
ZnO; Ag; Multilayer; Transparent conducting electrode; Organic solar cell; THIN-FILMS; POLYMER; DESIGN;
D O I
10.1016/j.cap.2015.05.001
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Inverted organic solar cells (OSCs) based on poly (3-hexylthiophene) (P3HT):[ 6,6]-phenyl-C61 butyric acid methyl ester (PCBM) bulk heterojunctions (BHJ) were fabricated with optimized ZnO/Ag/ZnO multilayer and conventional indium-tin oxide (ITO) cathode electrodes and their performance was compared. The ZnO/Ag/ZnO multilayer films showed sheet resistances in the range 3.6-3.9 Omega/sq, while ITO exhibited 14.2 Omega/sq. On the one hand, the carrier concentration gradually decreased from 1.74 x 10(22) to 4.33 x 10(21) cm(-3) as the ZnO thickness increased from 8 to 80 nm, respectively. The transmittance of the ZnO(40 nm)/Ag(19 nm)/ZnO(40 nm) films was similar to 95% at 550 nm, which is comparable to that of ITO (similar to 96%). The multilayer films were smooth with a root mean square (RMS) roughness of 0.81 nm. OSCs fabricated with the ZnO(40 nm)/Ag(19 nm)/ZnO(40 nm) film showed a power conversion efficiency (2.63%) comparable to that of OSCs with a conventional ITO cathode (2.71%). (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:829 / 832
页数:4
相关论文
共 31 条
[11]   Air-stable inverted flexible polymer solar cells using zinc oxide nanoparticles as an electron selective layer [J].
Hau, Steven K. ;
Yip, Hin-Lap ;
Baek, Nam Seob ;
Zou, Jingyu ;
O'Malley, Kevin ;
Jen, Alex K. -Y. .
APPLIED PHYSICS LETTERS, 2008, 92 (25)
[12]   Interfacial modification to improve inverted polymer solar cells [J].
Hau, Steven K. ;
Yip, Hin-Lap ;
Acton, Orb ;
Baek, Nam Seob ;
Ma, Hong ;
Jen, Alex K. -Y. .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (42) :5113-5119
[13]   Transparent conducting Zr-doped In2O3 thin films for organic light-emitting diodes [J].
Kim, H ;
Horwitz, JS ;
Kushto, GP ;
Qadri, SB ;
Kafafi, ZH ;
Chrisey, DB .
APPLIED PHYSICS LETTERS, 2001, 78 (08) :1050-1052
[14]   Inductively coupled plasma reactive ion etching of ZnO using BCI3-based plasmas [J].
Kim, HK ;
Bae, JW ;
Kim, TK ;
Kim, KK ;
Seong, TY ;
Adesida, I .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2003, 21 (04) :1273-1277
[15]   Dependences of Sputtering Times on the Structural and Electrical Properties of ZnO/Ag/ZnO Thin Films on PET by DC Sputtering [J].
Kim, Yun-Hae ;
Lee, Jin-Woo ;
Murakami, Ri-Ichi .
IEEE TRANSACTIONS ON NANOTECHNOLOGY, 2013, 12 (06) :991-995
[16]   Using Light-Induced Thermocleavage in a Roll-to-Roll Process for Polymer Solar Cells [J].
Krebs, Frederik C. ;
Norrman, Kion .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (03) :877-887
[17]  
Lagemaat J.V., 2006, APPL PHYS LETT, V88, P233503
[18]   Efficient inverted polymer solar cells [J].
Li, G. ;
Chu, C. -W. ;
Shrotriya, V. ;
Huang, J. ;
Yang, Y. .
APPLIED PHYSICS LETTERS, 2006, 88 (25)
[19]   Highly efficient inverted polymer solar cell by low temperature annealing of Cs2CO3 interlayer [J].
Liao, Hua-Hsien ;
Chen, Li-Min ;
Xu, Zheng ;
Li, Gang ;
Yang, Yang .
APPLIED PHYSICS LETTERS, 2008, 92 (17)
[20]   Effect of substrate temperature on the properties of Ti-doped ZnO films by simultaneous rf and dc magnetron sputtering [J].
Lin, SS ;
Huang, JL ;
Lii, DF .
MATERIALS CHEMISTRY AND PHYSICS, 2005, 90 (01) :22-30