Excellent enantio-selective enclathration of (2R,3S)-3-methyl-2-pentanol in channel-like cavity of 3-epideoxycholic acid, interpreted by the four-location model for chiral recognition

被引：25

作者：

Kato, K ^{[1
]}

Aburaya, K ^{[1
]}

Miyake, Y ^{[1
]}

Sada, K ^{[1
]}

Tohnai, N ^{[1
]}

Miyata, M ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 23期

关键词：

D O I：

10.1039/b309755b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pure ( 2R, 3S)- 3- methyl- 2- pentanol is resolved from the racemates by a steroidal host; the interpretation of the recognition mechanism based on the crystal structure reveals that CH/ O interaction between the host and guest plays a decisive role in enantio- selective enclathration of the small aliphatic secondary alcohol.

引用

页码：2872 / 2873

页数：2

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