Metallabenzenes

被引：347
作者：
Bleeke, JR [1 ]
机构：
[1] Washington Univ, Dept Chem, St Louis, MO 63130 USA
来源：
CHEMICAL REVIEWS | 2001年 / 101卷 / 05期
关键词：
D O I：
10.1021/cr990337n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A comprehensive study of the chemistry of transition-metal-containing metallabenzenes was carried out. Metallabenzenes represent a new class of aromatic compounds, in which metal d orbitals participate fully with carbon p orbitals in the formation of ring π-bonds. The results showed that the metallabenzenes are more prone to isomerization reactions than are conventional arenes.
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收藏
页码：1205 / 1227
页数：23
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