Technical and economic evaluation of supercritical CO2 extraction of oil from sucupira branca seeds

被引:24
作者
Chani-Paucar, Larry Oscar [1 ,2 ]
Johner, Julio Cezar Flores [1 ]
Zabot, Giovani L. [3 ]
Meireles, Maria Angela A. [1 ]
机构
[1] Univ Campinas UNICAMP, LASEFI Sch Food Engn FEA, R Monteiro Lobato 80, BR-13083862 Campinas, SP, Brazil
[2] Univ Nacl Amazanica Madre de Dios UNAMAD, Escuela Profes Ingn Agroind, Av Jorge Chavez S-N, Madre De Dios 17001, Peru
[3] Fed Univ Santa Maria UFSM, Lab Agroind Proc Engn LAPE, 1040 Sete Setembro St, BR-96508010 Cachoeira Do Sul, RS, Brazil
关键词
COM; Cost of manufacturing; Kinetic curves; Supercritical fluid extraction (SFE); CARBON-DIOXIDE EXTRACTION; VOLATILE OIL; FLUID EXTRACTION; BIOACTIVE COMPOUNDS; BETA-CARYOPHYLLENE; ALPHA-HUMULENE; RICH;
D O I
10.1016/j.supflu.2021.105494
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Supercritical CO2 extraction of sucupira branca (SB) seeds was studied under different conditions of pressure (20-40 MPa) and temperature (40 and 60 degrees C). Operational conditions were assessed on laboratory and pilot scales, and their influences on manufacturing cost (COM) and productivity were discussed. At 40 degrees C and 30 MPa for 65 min, 40 g oil/100 g SB seeds were obtained. In the economic and technical approaches, a plant with two extractors (2 x 15 L) is more convenient to implement than a plant with one extractor (1 x 30 L), obtaining a COM of 49.21 US$/kg SB oil and productivity of 20,083 kg oil/year. This COM and productivity were reached at the kinetic point where the S/F was 13.5 g CO2/g SB seeds. In this period, the mass transfer is controlled by diffusion and convection (FER period). The oil obtained under these conditions presented phytochemicals, such as alpha-humulene, beta-caryophyllene, alpha-copaene, (-)-beta-elemene, (E)-germacrene D(-)-gamma-elemene, and spathulenol.
引用
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页数:12
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