Mesoporous Pt/Ru alloy from the hexagonal lyotropic liquid crystalline phase of a nonionic surfactant

被引:117
作者
Attard, GS [1 ]
Leclerc, SAA [1 ]
Maniguet, S [1 ]
Russell, AE [1 ]
Nandhakumar, I [1 ]
Bartlett, PN [1 ]
机构
[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
关键词
D O I
10.1021/cm000850d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mesoporous and well-mixed Pt/Ru alloys (1:1 atomic ratio) were prepared by co-reduction of metal salts in the hexagonal Liquid crystalline phase of a nonionic surfactant. Preliminary data indicate that oxidation of carbon monoxide by the mesoporous alloy is more facile than by a commercial platinum catalyst or by mesoporous platinum.
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页码:1444 / +
页数:4
相关论文
共 17 条
[1]   Mesoporous platinum films from lyotropic liquid crystalline phases [J].
Attard, GS ;
Bartlett, PN ;
Coleman, NRB ;
Elliott, JM ;
Owen, JR ;
Wang, JH .
SCIENCE, 1997, 278 (5339) :838-840
[2]  
Attard GS, 1998, STUD SURF SCI CATAL, V117, P89
[3]   Liquid-crystal templates for nanostructured metals [J].
Attard, GS ;
Goltner, CG ;
Corker, JM ;
Henke, S ;
Templer, RH .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (12) :1315-1317
[4]  
Barth T, 1926, Z PHYS CHEM-STOCH VE, V121, P78
[5]  
BINSTED N, 1998, EXCURV98CCLRC DARESB
[6]  
COLEMAN NRB, 1999, THESIS U SOUTHAMPTON
[7]   Catalysis by palladium nanoparticles in microemulsions [J].
de Jesus, DM ;
Spiro, M .
LANGMUIR, 2000, 16 (11) :4896-4900
[8]   ELECTROOXIDATION OF SMALL ORGANIC-MOLECULES ON WELL-CHARACTERIZED PT-RU ALLOYS [J].
GASTEIGER, HA ;
MARKOVIC, N ;
ROSS, PN ;
CAIRNS, EJ .
ELECTROCHIMICA ACTA, 1994, 39 (11-12) :1825-1832
[9]   Performance and structure of Pt-Rh three-way catalysts: Mechanism for Pt/Rh synergism [J].
Hu, Z ;
Allen, FM ;
Wan, CZ ;
Heck, RM ;
Steger, JJ ;
Lakis, RE ;
Lyman, CE .
JOURNAL OF CATALYSIS, 1998, 174 (01) :13-21
[10]   IN-SITU X-RAY-ABSORPTION STUDIES OF A PT-RU ELECTROCATALYST [J].
MCBREEN, J ;
MUKERJEE, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (10) :3399-3404