1D+3D two-phase flow numerical model of a proton exchange membrane fuel cell

被引:126
作者
Ferreira, Rui B. [1 ]
Falcao, D. S. [1 ]
Oliveira, V. B. [1 ]
Pinto, A. M. F. R. [1 ]
机构
[1] Univ Porto, Fac Engn, Chem Engn Dept, Transport Phenomena Res Ctr CEFT, Rua Dr Roberto Frias, P-4200465 Oporto, Portugal
关键词
PEM fuel cells; Water management; Two-phase flow; Numerical model; Volume of fluid method; LIQUID WATER TRANSPORT; GAS-DIFFUSION LAYER; VALIDATED LEVERETT APPROACH; MULTIPHASE FLOW; CAPILLARY-PRESSURE; CATHODE CHANNEL; POROUS-MEDIA; AIR-CATHODE; VISUALIZATION; SIMULATION;
D O I
10.1016/j.apenergy.2017.06.048
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this work, a numerical model of a proton exchange membrane (PEM) fuel cell is presented. The volume of fluid (VOF) method is employed to simulate the air-water two-phase flow in the cathode gas channel, at the same time that the cell electrochemical performance is predicted. The model is validated against an experimental polarization curve and through the visualization of water distribution inside a transparent fuel cell. The water dynamics inside a serpentine gas channel is numerically analyzed under different operating voltages. Moreover, water content in different regions of the channel is quantified. Current density and water generation rate spatial distributions are also displayed and it is shown how they affect the process of water emergence into the gas channel. Important issues on the simulation of the PEM fuel cells two-phase flow are addressed, especially concerning the coupling of the VOF technique with electrochemical reactions. Both the model and the numerical results aim to contribute to a better understanding of the two-phase flow phenomenon that occurs in these devices. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:474 / 495
页数:22
相关论文
共 76 条
[51]   Effective diffusivity and water-saturation distribution in single- and two-layer PEMFC diffusion medium [J].
Nam, JH ;
Kaviany, M .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2003, 46 (24) :4595-4611
[52]  
O'Hayre R., 2006, Fuel Cell Fundamentals, V1
[53]   Two-phase modeling and flooding prediction of polymer electrolyte fuel cells [J].
Pasaogullari, U ;
Wang, CY .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (02) :A380-A390
[54]   A review on water fault diagnosis of PEMFC associated with the pressure drop [J].
Pei, Pucheng ;
Li, Yuehua ;
Xu, Huachi ;
Wu, Ziyao .
APPLIED ENERGY, 2016, 173 :366-385
[55]   Main factors affecting the lifetime of Proton Exchange Membrane fuel cells in vehicle applications: A review [J].
Pei, Pucheng ;
Chen, Huicui .
APPLIED ENERGY, 2014, 125 :60-75
[56]   Study of water distribution and transport in a polymer electrolyte fuel cell using neutron imaging [J].
Pekula, N ;
Heller, K ;
Chuang, PA ;
Turhan, A ;
Mench, MM ;
Brenizer, JS ;
Ünlü, K .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2005, 542 (1-3) :134-141
[57]   Numerical study of water management in the air flow channel of a PEM fuel cell cathode [J].
Quan, Peng ;
Lai, Ming-Chia .
JOURNAL OF POWER SOURCES, 2007, 164 (01) :222-237
[58]   Numerical Simulation of Two-Phase Water Behavior in the Cathode of an Interdigitated Proton Exchange Membrane Fuel Cell [J].
Quan, Peng ;
Lai, Ming-Chia .
JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY, 2010, 7 (01) :0110171-01101714
[59]   Non-equilibrium two-phase model of the air-cathode of a PEM fuel cell based on GDL experimental water transport characteristics [J].
Ramos-Alvarado, Bladimir ;
Hernandez-Guerrero, Abel ;
Ellis, Michael W. .
JOURNAL OF POWER SOURCES, 2013, 232 :376-388
[60]   In situ neutron imaging technique for evaluation of water management systems in operating PEM fuel cells [J].
Satija, R ;
Jacobson, DL ;
Arif, M ;
Werner, SA .
JOURNAL OF POWER SOURCES, 2004, 129 (02) :238-245