Electrical characteristics of Li(Ni7/10Fe3/10)VO4 ceramics

被引：32

作者：

Ram, Moti ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Phys & Meteorol, Kharagpur 721302, W Bengal, India

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2011年 / 509卷 / 05期

关键词：

Ceramics; Solution-based chemical method; Complex impedance spectroscopy; ELECTROCHEMICAL PROPERTIES; DIELECTRIC-PROPERTIES; ELECTRONIC-STRUCTURE; IMPEDANCE; OXIDE; LIFE1/2NI1/2VO4; SPECTROSCOPY; BATTERIES; COMPOUND; LIFEVO4;

D O I：

10.1016/j.jallcom.2010.09.212

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The compound [Li(Ni7/10Fe3/10)VO4] was produced by a solution-based chemical route whose electrical properties were investigated using complex impedance spectroscopy technique. X-ray diffraction study reveals an orthorhombic unit cell structure of the compound. Complex electrical impedance analysis exhibits: (i) grain interior, grain boundary and electrode-material interface contributions to electrical response and (ii) the presence of temperature dependent electrical relaxation phenomena in the material. Electrical conductivity study indicates that electrical conduction in the material is a thermally activated process. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1744 / 1748

页数：5

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