Enantiospecific synthesis of 8-epipuupehedione from (R)-(-)-carvone

被引：37

作者：

Maiti, S ^{[1
]}

Sengupta, S ^{[1
]}

Giri, C ^{[1
]}

Achari, B ^{[1
]}

Banerjee, AK ^{[1
]}

机构：

[1] Indian Inst Chem Biol, Dept Med Chem, Kolkata 700032, W Bengal, India

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 12期

关键词：

D O I：

10.1016/S0040-4039(01)00153-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An enantiospecific synthesis of the antitumor marine sponge metabolite puupehedione (2a) and its C-8-epimer 2b as their methylenedioxy derivatives 8a and 8b was achieved through concomitant O-allyl deprotection and electrocyolization of 20 derived from (-)-carvone. (C) 2001 Published by Elsevier Science Ltd.

引用

页码：2389 / 2391

页数：3

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