Extraction of Lanthanide Nitrates in Multicomponent Aqueous-Organic Two-Phase Systems with D2EHPA

被引：6
作者：
Belova, V. V. [1 ]
Martynova, M. M. [1 ]
Erastov, A. A. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 63卷 / 12期
基金：
俄罗斯基础研究基金会;
关键词：
lanthanide nitrates; di(2-ethylhexyl) phosphoric acid; multicomponent aqueous-organic biphasic systems; interphase distribution; separation; COUNTER-CURRENT CHROMATOGRAPHY; LIQUID-LIQUID CHROMATOGRAPHY; CENTRIFUGAL PARTITION CHROMATOGRAPHY; PHOSPHORIC-ACID; SAMPLE INJECTION; STEADY-STATE; SEPARATION; MODE; MIXTURE; CELL;
D O I：
10.1134/S0036023618120033
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Lanthanum nitrate distribution in three-component aqueous-organic systems with D2EHPA from acetate or acetic acid-acetate solutions has been studied, it has been shown that variation in sodium acetate concentration or composition of CH3COONa-CH3COOH mixture can affect metal distribution ratios. It has been found that extraction in three-component mixture of 1: 1: 1 composition (aqueous solution Ln(NO3)(3) + CH3COONa + CH3COOH-D2EHPA in hexane-isopropyl alcohol) can provide lanthanide separation, which is dependent on the ratio of sodium acetate and acetic acid in aqueous phase and on D2EHPA concentration in organic phase. Lanthanide-lanthanum separation factors have been calculated for the extraction of lanthanide nitrates from acetic acid-acetate solutions.
引用
收藏
页码：1651 / 1655
页数：5
相关论文
共 50 条
  • [41] Harvesting microalgae using ionic polyelectrolytes in an aqueous-organic two-phase system: Screening of separation parameters using model algal particles
    Gejji, Varun
    Fernando, Sandun D.
    [J]. PROCESS BIOCHEMISTRY, 2018, 72 : 188 - 197
  • [42] Mass transfer kinetics of lanthanum (III) extraction in the presence of two complexing agents by D2EHPA using a constant interfacial area cell with laminar flow
    Yin, Shaohua
    Li, Shiwei
    Zhang, Bo
    Peng, Jinhui
    Zhang, Libo
    [J]. CHEMICAL ENGINEERING RESEARCH & DESIGN, 2015, 104 : 92 - 97
  • [43] Optimization of the gallic acid extraction using ionic-liquid-based aqueous two-phase systems
    Claudio, Ana Filipa M.
    Ferreira, Ana M.
    Freire, Carmen S. R.
    Silvestre, Armando J. D.
    Freire, Mara G.
    Coutinho, Joao A. P.
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2012, 97 : 142 - 149
  • [44] Extraction of geniposidic acid and aucubin employing aqueous two-phase systems comprising ionic liquids and salts
    Wang, Yicong
    Wang, Shanshan
    Liu, Leilei
    [J]. MICROCHEMICAL JOURNAL, 2021, 169
  • [45] Formation of Aqueous Two-Phase Systems Using Potassium Salt and Deep Eutectic Mixtures for Extraction of Proteins
    Marappan, Saravanakumara
    Kamaruddin, Azlina Harun
    Gonawan, Fadzil Noor
    [J]. CHEMICAL ENGINEERING & TECHNOLOGY, 2023, 46 (12) : 2497 - 2503
  • [46] Enantioselective Extraction of Phenylalanine Enantiomers Using Environmentally Friendly Aqueous Two-Phase Systems
    Sun, Danyu
    Wang, Runping
    Li, Fenfang
    Liu, Lianglei
    Tan, Zhijian
    [J]. PROCESSES, 2018, 6 (11):
  • [47] Design of environmentally friendly ionic liquid aqueous two-phase systems for the efficient and high activity extraction of proteins
    Li, Zhiyong
    Liu, Xinxin
    Pei, Yuanchao
    Wang, Jianji
    He, Mingyuan
    [J]. GREEN CHEMISTRY, 2012, 14 (10) : 2941 - 2950
  • [48] Synthesis of pH-responsive polymers forming recyclable aqueous two-phase systems and application to the extraction of demeclocycline
    Gai, Zhiliang
    Wan, Junfen
    Cao, Xuejun
    [J]. BIOCHEMICAL ENGINEERING JOURNAL, 2019, 142 : 89 - 96
  • [49] Extraction mechanism of sulfamethoxazole in water samples using aqueous two-phase systems of poly(propylene glycol) and salt
    Xie, Xuegiao
    Wang, Yun
    Han, Juan
    Yan, Yongsheng
    [J]. ANALYTICA CHIMICA ACTA, 2011, 687 (01) : 61 - 66
  • [50] Optimized extraction of a single-chain variable fragment of antibody by using aqueous micellar two-phase systems
    Malpiedi, Luciana P.
    Nerli, Bibiana B.
    Taqueda, Maria E. S.
    Abdalla, Dulcineia S. P.
    Pessoa, Adalberto, Jr.
    [J]. PROTEIN EXPRESSION AND PURIFICATION, 2015, 111 : 53 - 60
12345