An Alternative Mechanism for the Cobalt-Catalyzed Isomerization of Terminal Alkenes to (Z)-2-Alkenes

被引：78

作者：

Schmidt, Anastasia ^{[1
]}

Noedling, Alexander R. ^{[1
]}

Hilt, Gerhard ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 03期

关键词：

alkenes; cobalt; double-bond migration; isomerization; stereoselectivity; COMPLEXES; 1-ALKENES; OLEFINS;

D O I：

10.1002/anie.201409902

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cobalt-catalyzed selective isomerization of terminal alkenes to the thermodynamically less-stable (Z)-2-alkenes at ambient temperatures takes place by a new mechanism involving the transfer of a hydrogen atom from a Ph2PH ligand to the starting material and the formation of a phosphenium complex, which recycles the Ph2PH complex through a 1,2-H shift.

引用

页码：801 / 804

页数：4

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