The Application of Zinc Oxide Nanoparticles as An Eco-Friendly Inhibitor for Steel in Acidic Solution

被引:24
作者
Al-Dahiri, Reema H. [1 ]
Turkustani, Aisha M. [1 ,2 ]
Salam, Mohamed Abdel [1 ]
机构
[1] King Abdulaziz Univ, Fac Sci Girls, Chem Dept, POB 80200, Jeddah 21589, Saudi Arabia
[2] Jeddah Univ, Fac Sci Girls, Chem Dept, Jeddah, Saudi Arabia
关键词
corrosion; steel; Myrrh; green synthesis; zinc oxide nanoparticles; GREEN CORROSION-INHIBITOR; M HCL SOLUTION; MILD-STEEL; HYDROCHLORIC-ACID; CARBON-STEEL; SULFURIC-ACID; EXTRACT; NANOTECHNOLOGY; DERIVATIVES; IRON;
D O I
10.20964/2020.01.01
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this study, zinc oxide nanoparticles were prepared using a natural extract of Myrrh as green capping agent. The synthesized ZnO-NPs (Zinc Oxide Nanoparticles) were characterized using XRD and scanning electron microscopy, and the results revealed the synthesis of hexagonal wurtzite ZnO-NPs. The corrosion inhibition of steel in 1.0 M HC1 using an aqueous extract of natural Myrrh and the greensynthesized ZnO-NPs was investigated at various concentrations using electrochemical impedance spectroscopy (EIS) measurements and potentiodynamic polarization (PDP). The results revealed that the corrosion inhibition process is exponentially increased with the inhibitor concentrations, and an inhibition effectiveness of 92% could be acquired. Polarization curves showed that the eco-friendly inhibitors perform as a cathodic inhibitor. Consequently, the obtained inhibition efficiency values derived from all chosen analysis techniques were in reasonably good agreement.
引用
收藏
页码:442 / 457
页数:16
相关论文
共 53 条
[1]  
Abdallah M., 2004, Port. Electrochim. Acta, V22, P161
[2]  
Abu-Dalo MA, 2012, INT J ELECTROCHEM SC, V7, P9303
[3]  
Adams F., 2015, Comprehensive Analytical Chemistry, P125
[4]   Epoxy in nanotechnology: A short review [J].
Ahmadi, Zahed .
PROGRESS IN ORGANIC COATINGS, 2019, 132 :445-448
[5]  
Al-Turkustani AM, 2013, J CHEM ACTA, V2, P253
[6]   Preparation of Semiconductor Zinc Oxide Nanoparticles as a Photocatalyst to Get Rid of Organic Dyes Existing Factories in Exchange for Reuse in Suitable Purpose [J].
Alhadhrami, A. ;
Almalki, Abdulraheem S. A. ;
Adam, Abdel Majid A. ;
Refat, Moamen S. .
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2018, 13 (07) :6503-6521
[7]  
Atta AM, 2014, INT J ELECTROCHEM SC, V9, P8446
[8]   Inhibitive properties and surface morphology of a group of heterocyclic diazoles as inhibitors for acidic iron corrosion [J].
Babic-Samardzija, K ;
Lupu, C ;
Hackerman, N ;
Barron, AR ;
Luttge, A .
LANGMUIR, 2005, 21 (26) :12187-12196
[9]   Gum Arabic as an eco-friendly inhibitor for API 5L X42 pipeline steel in HCl medium [J].
Bentrah, Hamza ;
Rahali, Youssouf ;
Chala, Abdelouahad .
CORROSION SCIENCE, 2014, 82 :426-431
[10]   Influence of self-doped poly(aniline-co-4-amino-3-hydroxy-naphthalene-1-sulfonic acid) on corrosion inhibition behaviour of iron in acidic medium [J].
Bhandari, Hema ;
Choudhary, Veena ;
Dhawan, S. K. .
SYNTHETIC METALS, 2011, 161 (9-10) :753-762