A convenient one-pot synthesis of 1,2-azaphospholanium salts

被引：10

作者：

Aladzheva, IM ^{[1
]}

Lobanov, DI ^{[1
]}

Bykhovskaya, OV ^{[1
]}

Petrovskii, PV ^{[1
]}

Lyssenko, KA ^{[1
]}

Mastryukova, TA ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

HETEROATOM CHEMISTRY | 2003年 / 14卷 / 07期

关键词：

D O I：

10.1002/hc.10209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel facile one-pot synthesis of the 1,2-azaphospholanes by intramolecular alkylation of 3-halopropyl amides of tricoordinate phosphorus has been suggested. Using this method, a series of the differently N-substituted 1,2-azaphospholanium salts were synthesized. 3-Aminopropylphosphine oxides were obtained by hydrolysis of the salts. A probable mechanism of the 1,2-azaphospholanium salts formation is discussed. (C) 2003 Wiley Periodicals, Inc.

引用

页码：596 / 602

页数：7

共 11 条

[1] Aladzheva IM, 2002, KHIM GETEROTSIKL+, P105
[2] Aladzheva IM, 1998, ZH OBSHCH KHIM+, V68, P1421
[3] BYKHOVSKAYA OV, 2001, ZH OBSHCH KHIM, V0071
[4] CLEMENS FD, 1965, INORG CHEM, V4, P1222
[5] CONFORMATIONAL EFFECTS ON P-N-P COUPLING-CONSTANTS IN DIPHOSPHINOAMINES AND RELATED COMPOUNDS
CROSS, RJ
GREEN, TH
KEAT, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (14): : 1424 - 1428
[6] KEAT R, 1981, J CHEM SOC DALTON, P2192, DOI 10.1039/dt9810002192
[7] Sakai T, 1996, HETEROCYCL COMMUN, V2, P233
[8] SYNTHESIS AND AZA-WITTIG REACTIONS OF CYCLIC AMINO PHOSPHONIUM SALTS
SAKAI, T
KODAMA, T
FUJIMOTO, T
OHTA, K
YAMAMOTO, I
KAKEHI, A
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (23) : 7144 - 7147
[9] Novel chiral phosphine ligands and complexes from amino acid esters
Slawin, AMZ
Woollins, JD
Zhang, QZ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (05): : 621 - 632
[10] Reactions of cyclic aza-ylides with β-dicarbonyl compounds
Uchiyama, T
Inoue, M
Masuda, H
Fujimoto, T
Yamamoto, I
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2001, 175 : 99 - 108

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