Synthesis and luminescence properties of SBA-15 functionalized with covalently bonded ternary europium complex

被引:35
|
作者
Peng, CY
Zhang, HJ
Meng, QG
Li, HR
Yu, JB
Guo, JF
Sun, LN
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
基金
中国国家自然科学基金;
关键词
SBA-15; covalently bonded; europium complex; luminescence;
D O I
10.1016/j.inoche.2005.01.026
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Novel hybrid materials containing covalently bonded ternary europium complex in mesoporous silica SBA-15 have been successfully prepared by co-condensation of the modified phenanthroline (phen-Si) and tetrethoxysilane (TEOS). When excited by the ligands absorption wavelength (352 nm), Eu(TTA)(3)phen (TTA: 2-thenoyltrifluoroacetone) functionalized SBA-15 displays the emission of the Eu3+ D-5(0) -> F-7(J) (J = 0, 1, 2, 3, 4) transition lines due to the efficient energy transfer from the ligands to Eu3+. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:440 / 443
页数:4
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