Alkylation of benzene with 1-octene over rare earth exchanged HFAU-Y zeolites

被引：2

作者：

Thomas, B ^{[1
]}

Sugunan, S ^{[1
]}

机构：

[1] Cochin Univ Sci & Technol, Dept Appl Chem, Kerala 682022, India

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2005年 / 85卷 / 01期

关键词：

rare earth exchanged zeolites; linear alkylbenzene; Hirshler-Plank mechanism;

D O I：

10.1007/s11144-005-0239-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Binder free HFAU-Y was exchanged with various rare earth metals such as cerium, lanthanum, and mixed rare earths (named as HRE-Y), in order to improve the textural, structural, catalytic properties, and stability towards vigorous reaction conditions. These as-exchanged zeolites have been effectively employed for the alkylation of benzene with 1-octene. All the systems perpetually show greater selectivity towards the most desired 2-phenyloctane.

引用

页码：29 / 36

页数：8

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