Revision of the model of formation of radiolytic products in aqueous solutions

被引:4
|
作者
Stepanov, SV [1 ]
Byakov, VM [1 ]
机构
[1] Inst Theoret & Expt Phys, Moscow 117218, Russia
关键词
D O I
10.12693/APhysPolA.107.651
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Mathematical model of formation of radiolytic products (e(aq)(-), H, OH, H-2, H3O+, OH--, Ps) in water is developed. It takes into account (1) reactions between dissolved scavengers of thermalized and hydrated electrons as well as epithermal ones; (2) ambipolar diffusion expansion of the intratrack species; (3) additional channels of Ps and H-2 formation due to appearance of weakly trapped electrons. Good agreement is obtained with experimental data on kinetics, of accumulation of the products in pure water and their concentration variations in aqueous solutions.
引用
收藏
页码:651 / 660
页数:10
相关论文
共 50 条
  • [31] Plasmon-assisted radiolytic energy conversion in aqueous solutions
    Kim, Baek Hyun
    Kwon, Jae W.
    SCIENTIFIC REPORTS, 2014, 4
  • [32] Effect of formate on the radiolytic degradation of nitrate in deaerated aqueous solutions
    Ponomarev, AV
    Bludenko, AV
    Makarov, IF
    MENDELEEV COMMUNICATIONS, 2002, (03) : 92 - 94
  • [33] The unusual radiolytic behavior of neptunium ions in aqueous bicarbonate solutions
    Shilov, VP
    Gogolev, AV
    Pikaev, AK
    DOKLADY PHYSICAL CHEMISTRY, 2000, 375 (1-3) : 245 - 248
  • [34] Plasmon-assisted radiolytic energy conversion in aqueous solutions
    Baek Hyun Kim
    Jae W. Kwon
    Scientific Reports, 4
  • [35] CdSe nanoparticles grown via radiolytic methods in aqueous solutions
    Singh, Shalini
    Rath, M. C.
    Singh, A. K.
    Mukherjee, T.
    Jayakumar, O. D.
    Tyagi, A. K.
    Sarkar, S. K.
    RADIATION PHYSICS AND CHEMISTRY, 2011, 80 (06) : 736 - 741
  • [36] A study of radiolytic gas formation in nitrate and acetate solutions
    Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117915, Russia
    High Energy Chem., 6 (365-367):
  • [37] Specifics of Radiolytic Degradation of Oxalic Acid in Aerated Aqueous Solutions
    Zhestkova, T. P.
    Zhukova, T. N.
    Makarov, I. E.
    HIGH ENERGY CHEMISTRY, 2011, 45 (02) : 85 - 88
  • [38] RADIOLYTIC REDUCTION OF TRIOXALATOFERRATE(III) IONS IN AQUEOUS-SOLUTIONS
    SHARMA, BK
    SARAN, P
    RADIATION PHYSICS AND CHEMISTRY, 1982, 19 (03): : 197 - 200
  • [39] A study of radiolytic gas formation in nitrate and acetate solutions
    Stelmakh, NS
    Kritskaya, VE
    Byvsheva, IT
    Pirogova, GN
    Kosareva, IM
    HIGH ENERGY CHEMISTRY, 1997, 31 (06) : 365 - 367
  • [40] THE RADIOLYTIC REDUCTION OF MERCURIC-CHLORIDE IN AQUEOUS SUGAR SOLUTIONS
    JOHNSTON, FJ
    RADIATION PHYSICS AND CHEMISTRY, 1991, 37 (02): : 291 - 294