Rotational alignment from the reactions Sr(3Pj)+CCl4 and CHCl3

被引：13
|
作者：
Wang, ML [1 ]
Han, KL [1 ]
Zhan, JP [1 ]
Huang, JH [1 ]
He, GZ [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
来源：
CHEMICAL PHYSICS | 1998年 / 236卷 / 1-3期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1016/S0301-0104(98)00194-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Sr(P-3(J)) + CHnCl4-n(n = 0, 1) --> SrCl(A (2)Pi(1/2, 3/2); B (2)Sigma(+)) + CHnCl3-n reactions have been studied by measuring their chemiluminescence under beam-gas conditions. The rotational alignments of the product SrCl(B (2)Sigma(+)) are obtained from Sr(P-3(J)) + CHnCl4-n(n = 0, 1) chemiluminescence. In addition, the electronic state branching ratio and the product vibrational state population have been roughly estimated by simulating the chemiluminescent spectrum of SrCl. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：387 / 392
页数：6
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