Glass fibre sizings with distinguished thermal properties are developed for improved ageing performance at high process temperature conditions (up to 300 degrees C) in combination with enhanced interfacial adhesion in glass fibre reinforced polyamide 66 matrix composites. Investigations on glass fibre sizing formulations, consisting of combinations of amino propyltriethoxysilane and polyurethane, polyacrylate or epoxy film formers are presented. Using thermo-gravimetric analyses coupled with Fourier transform infrared spectrometry, the influence of the sizing composition on the thermal degradation behaviour is examined. Besides, composites are thermal-oxidatively aged in order to detect the influence of the sizing on their thermal stability. We show that appropriate sizing improves both composite mechanical properties and the ageing stability as indicated by the temperature-time-limit parameters, in which the efficiency is strongly dependent on the silane/film former combination. (C) 2010 Elsevier Ltd. All rights reserved.
机构:
Univ Maine, LAUM, UMR 6613, CNRS, Ave O Messiaen, F-72085 Le Mans 9, France
Ecole Natl Ingn Sfax, Lab Modelisat Mecan & Prod, Sfax, TunisiaUniv Maine, LAUM, UMR 6613, CNRS, Ave O Messiaen, F-72085 Le Mans 9, France
Hammami, M.
El Mahi, A.
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Univ Maine, LAUM, UMR 6613, CNRS, Ave O Messiaen, F-72085 Le Mans 9, FranceUniv Maine, LAUM, UMR 6613, CNRS, Ave O Messiaen, F-72085 Le Mans 9, France
El Mahi, A.
Karra, C.
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Ecole Natl Ingn Sfax, Lab Modelisat Mecan & Prod, Sfax, TunisiaUniv Maine, LAUM, UMR 6613, CNRS, Ave O Messiaen, F-72085 Le Mans 9, France
Karra, C.
Haddar, M.
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Ecole Natl Ingn Sfax, Lab Modelisat Mecan & Prod, Sfax, TunisiaUniv Maine, LAUM, UMR 6613, CNRS, Ave O Messiaen, F-72085 Le Mans 9, France
机构:
Univ Lille Nord France, Lille Sci & Technol 1, Lille, France
Ecole Mines Douai, Polymers & Composites Technol & Mech Engn Dept, 941 Rue Charles Bourseul,CS 10838, F-59508 Douai, FranceUniv Lille Nord France, Lille Sci & Technol 1, Lille, France
Coulon, A.
Lafranche, E.
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Univ Lille Nord France, Lille Sci & Technol 1, Lille, France
Ecole Mines Douai, Polymers & Composites Technol & Mech Engn Dept, 941 Rue Charles Bourseul,CS 10838, F-59508 Douai, FranceUniv Lille Nord France, Lille Sci & Technol 1, Lille, France
Lafranche, E.
Douchain, C.
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Univ Lille Nord France, Lille Sci & Technol 1, Lille, France
Ecole Mines Douai, Polymers & Composites Technol & Mech Engn Dept, 941 Rue Charles Bourseul,CS 10838, F-59508 Douai, FranceUniv Lille Nord France, Lille Sci & Technol 1, Lille, France
Douchain, C.
Krawczak, P.
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Univ Lille Nord France, Lille Sci & Technol 1, Lille, France
Ecole Mines Douai, Polymers & Composites Technol & Mech Engn Dept, 941 Rue Charles Bourseul,CS 10838, F-59508 Douai, FranceUniv Lille Nord France, Lille Sci & Technol 1, Lille, France
Krawczak, P.
Ciolczyk, J. P.
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Hutchinson SA, Res Dept, Paris, FranceUniv Lille Nord France, Lille Sci & Technol 1, Lille, France
Ciolczyk, J. P.
Gamache, E.
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Arkema Res Dept Serquigny, Serquigny, FranceUniv Lille Nord France, Lille Sci & Technol 1, Lille, France