Studies on cobalt-based Fischer-Tropsch catalyst and characterization using SEM and XPS techniques

被引:15
|
作者
Sharma, BK [1 ]
Sharma, MP
Kumar, S
Roy, SK
Roy, SK
Badrinarayanan, S
Sainkar, SR
Mandale, AB
Date, SK
机构
[1] Cent Fuel Res Inst, Dhanbad 828108, Bihar, India
[2] Natl Chem Lab, Special Instruments Lab, Poona 411008, Maharashtra, India
关键词
Fischer-Tropsch synthesis; catalyst modification; XPS and SEM studies;
D O I
10.1016/S0926-860X(00)00860-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper reports the results of an experimental study involving Fischer-Tropsch (FT) synthesis on modified Co/Si-2-Al2O3 catalyst. The objectives are to increase the selectivity of C-5(+) liquid hydrocarbons (HC) and to decrease the formation of gaseous hydrocarbons during the reaction. The catalysts were characterized by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and powder X-ray diffraction (XRD) techniques. The XPS results indicated the formation of a new surface species of cobalt complex on the surface of the catalyst. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:203 / 211
页数:9
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