Stereoselective synthesis and reaction of gold(I) (Z)-enethiolates

被引：8

作者：

Miyamoto, Kazunori ^{[1
,2
,3
]}

Hirobe, Masaya ^{[4
]}

Uchiyama, Masanobu ^{[1
,2
,3
]}

Ochiai, Masahito ^{[4
]}

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Tokyo, Japan

[2] RIKEN, Adv Elements Chem Res Team, RIKEN Ctr Sustainable Resource Sci, Wako, Saitama 3510198, Japan

[3] RIKEN, Elements Chem Lab, Wako, Saitama 3510198, Japan

[4] Univ Tokushima, Grad Sch Pharmaceut Sci, Tokushima 7708505, Japan

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 37期

关键词：

DERIVATIVES; THIOCARBONYLS; COMPLEXES; SILVER;

D O I：

10.1039/c5cc02000j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bench-top-storable (Z)-enethiol reagents: gold (Z)-1-decenylthiolates were synthesized stereoselectively in high yields. They are stable upon storage at room temperature without protection from light, and react smoothly with various alkyl halides, alpha,beta-unsaturated ketones, and electron-deficient aryl halides with excellent stereoselectivity.

引用

收藏

页码：7962 / 7965

页数：4

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