Stereoselective synthesis and reaction of gold(I) (Z)-enethiolates

被引：8
|
作者：
Miyamoto, Kazunori [1 ,2 ,3 ]
Hirobe, Masaya [4 ]
Uchiyama, Masanobu [1 ,2 ,3 ]
Ochiai, Masahito [4 ]
机构：
[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Tokyo, Japan
[2] RIKEN, Adv Elements Chem Res Team, RIKEN Ctr Sustainable Resource Sci, Wako, Saitama 3510198, Japan
[3] RIKEN, Elements Chem Lab, Wako, Saitama 3510198, Japan
[4] Univ Tokushima, Grad Sch Pharmaceut Sci, Tokushima 7708505, Japan
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 37期
关键词：
DERIVATIVES; THIOCARBONYLS; COMPLEXES; SILVER;
D O I：
10.1039/c5cc02000j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bench-top-storable (Z)-enethiol reagents: gold (Z)-1-decenylthiolates were synthesized stereoselectively in high yields. They are stable upon storage at room temperature without protection from light, and react smoothly with various alkyl halides, alpha,beta-unsaturated ketones, and electron-deficient aryl halides with excellent stereoselectivity.
引用
收藏
页码：7962 / 7965
页数：4
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